名古屋大学 大学院理学研究科 物質理学専攻(化学系) 無機化学研究室

原著論文

2020

@Nagoya Univ.

124) S. Muratsugu, S. Shirai, M. Tada "Recent Progress in Molecularly Imprinted Approach for Catalysis" Tetrahedron Lett., in press. DOI: 10.1016/j.tetlet.2020.151603. (Invited Digest)

123)S. Akiyama, S. Ikemoto, S. Muratsugu, M. Tada, M. Yamashita "Copper Complexes Bearing a Dianionic Diborane(4) Ligand: Synthesis and Evaluation of the Donor Property" Organometallics, in press. DOI: 10.1021/acs.organomet.0c00027.

2019

@名古屋大学

122) S. Ikemoto, X. Huang, S. Muratsugu, S. Nagase, T. Koitaya, H. Matsui, G. Yokota, T. Sudoh, A. Hashimoto, Y. Tan, S. Yamamoto, J. Tang, I. Matsuda, J. Yoshinobu, T. Yokoyama, S. Kusaka, R. Matsuda, and M. Tada “Reversible Low-Temperature Redox Activity and Selective Oxidation Catalysis Derived from Concerted Activation of Multiple Metal Species on Cr and Rh-Incorporated Ceria Catalysts” Phys. Chem. Chem. Phys., 31, 18844-18853 (2019). DOI:10.1039/C9CP04625A.

121) S. Morisako, S. Watanabe, S. Ikemoto, S. Muratsugu, M. Tada, and M. Yamashita “Synthesis of A Pincer-Ir(V) Complex with A Base-Free Alumanyl Ligand and Its Application toward Dehydrogenation of Alkanes” Angew. Chem. Int. Ed., 58, 15031-15035 (2019). DOI: 10.1002/anie.201909009

120) Y. Tan, H. Matsui, N. Ishiguro, T. Uruga, D. N. Nguyen, O. Sekizawa, T. Sakata, N. Maejima, K. Higashi, H. C. Dam, and M. Tada “PtCo/C Cathode Catalyst Degradation in a Polymer Electrolyte Fuel Cell Investigated by an Infographic Approach Combining Three-Dimensional Spectroimaging and Unsupervised Learning” J. Phys. Chem. C, 123, 31, 18844-18853 (2019).[Supplementary Cover of JPCC] DOI: 10.1021/acs.jpcc.9b05005

119) T. Uruga, M. Tada, O. Sekizawa, Y. Takagi, T. Yokoyama, and Y. Iwasawa “SPring-8 BL36XU: Synchrotron Radiation X-ray-based Multi-analytical Beamline for Polymer Electrolyte Fuel Cells under Operating Conditions” Chem. Rec. 19, 1444-1456 (2019). [Invited personal accounts] DOI: 10.1002/tcr.201800193,

118) H. Matsui, N. Maejima, N. Ishiguro, Y. Tan, T. Uruga, O. Sekizawa, T. Sakata, and M. Tada “Operando XAFS Imaging of Distribution of Pt Cathode Catalysts in PEFC MEA” Chem. Rec. 19, 1380-1392 (2019). [Invited personal accounts] DOI: 10.1002/tcr.201800123

117)M. Hirose, N. Ishiguro, K. Shimomura, D. N. Nguyen, H. Matsui, H. C. Dam, M. Tada, and Y. Takahashi “Oxygen-Diffusion-Driven Oxidation Behavior and Tracking Areas Visualized by X-ray Spectro-Ptychography with Unsupervised Learning” Commun. Chem. 2, 50 (2019). DOI: 10.1038/s42004-019-0147-y

116)Y. Ohki, R. Hara, K. Munakata, M. Tada, T. Takayama, Y. Sakai, and R. Cramer “Synthesis of [Mo3S4] Clusters from Half-Sandwich Mo(V) Chlorides and Their Application as Platforms for [Mo3S4Fe] Cubes” Inorg. Chem. 58, 5230-5240 (2019). DOI: 10.1021/acs.inorgchem.9b00309

115)K. Ichihashi, S. Muratsugu, S. Miyamoto, K. Sakamoto, N. Ishiguro, M. Tada "Enhanced Oxygen Reduction Reaction Performance of Size-controlled Pt Nanoparticles on Polypyrrole-Functionalized Carbon Nanotubes"
Dalton Trans., 48, 7130 - 7137 (2019). [Inside Front Cover ] DOI: 10.1039/C9DT00158A

114)L. Yu, Y. Takagi, T. Nakamura, T. Sakata, T. Uruga, M. Tada, Y. Iwasawa, S. Masaoka, and T. Yokoyama “Operando Observation of Sulfur Species Poisoning Polymer Electrolyte Fuel Cell Studied by Near Ambient Pressure Hard X-ray Photoelectron Spectroscopy” J. Phys. Chem. C 123, 603-611 (2019). 10.1021/acs.jpcc.8b10611

2018

@名古屋大学

113)Y. Ohki, K. Uchida, R. Hara, M. Kachi, M. Fujisawa, M. Tada, Y. Sakai, W. M. C. Sammera, "Cubane-Type [Mo3S4M] Clusters with First-Row Group 4-10 Transition-Metal Halides Supported by C5Me5 Ligands on Molybdenum" Chem. Eur. J. , 24, 17138-17147 (2018). DOI: 10.1002/chem.201804083

112)Y. Ohki, K. Uchida, M. Tada, R. E. Cramer, T. Ogura, and T. Ohta "N2 Activation on a Molybdenum-Titanium-Sulfur Cluster" Nature Commun. , 9, 3200 (2018). DOI: 10.1038/s41467-018-05630-6

111)Y. Tan, H. Matsui, N. Ishiguro, and M. Tada "Three-dimensional XAFS Imaging of Polymer Electrolyte Fuel Cell Cathode Catalysts in Membrane Electrode Assembly" Acc. Mater. Surf. Res. 3, 165-171 (2018). [Invited]

110)P. Tegeder, M. Freitag, K. M. Chepiga, S. Muratsugu, N. Moller, S. Lamping, M. Tada, F. Glorius, B. J. Ravoo "N-Heterocyclic Carbene-Modified AuPd Alloy Nanoparticles and their Application as Biomimetic and Heterogeneous Catalysts" Chem. Eur. J. , 24, 18682-18688 (2018). DOI:10.1002/chem.201803274

109)S. Ozawa, H. Matsui, N. Ishiguro, Y. Tan, N. Maejima, M. Taguchi, T. Uruga, O. Sekizawa, T. Sakata, K. Nagasawa, K. Higashi, and M. Tada "Operando Time-Resolved XAFS Study for Pt Oxidation Kinetics on Pt/C and Pt3Co/C Cathode Catalysts by PEFC Voltage Operation Synchronized with Rapid O2 Exposure" J. Phys. Chem. , 122, 14511-14517 (2018). DOI: 10.1021/acs.jpcc.8b02541

108)N. Ishiguro and M. Tada "Structural Kinetics of Cathode Events on Polymer Electrolyte Fuel Cell Catalysts Studied by Operando Time-resolved XAFS" Catal. Lett. , 148, 1597-1609 (2018). DOI: 10.1007/s10562-018-2383-7

107)S. Muratsugu, H. Baba, T. Tanimoto, K. Sawaguchi, S. Ikemoto, M. Tasaki, Y. Terao, M. Tada “Chemoselective Epoxidation of Cholesterol Derivatives on a Surface-Designed Molecularly Imprinted Ru-Porphyrin Catalyst” Chem. Commun. , 54, 5114-5117 (2018). DOI: 10.1039/C8CC00896E

106)S. Muratsugu, A. Yamaguchi, G.-i. Yokota, T. Maeno, M. Tada “Tuning the Structure and Catalytic Activity of Ru Nanoparticle Catalysts by Single 3d Transition-metal Atoms in Ru12-Metalloporphyrin Precursors” Chem. Commun. , 54, 4842-4845 (2018). DOI: 10.1039/C7CC09862F

105)M. Hirose, N. Ishiguro, K. Shimomura, D. Burdet, H. Matsui, M. Tada, Y. Takahashi "Visualization of Heterogeneous Oxygen Storage Behavior in Platinum-Supported Cerium-Zirconium Oxide Three-Way Catalyst Particles by Hard X-ray Spectro-Ptychography" Angew. Chem. Int. Ed. , 57, 1474 (2018). DOI: 10.1002/anie.201710798

2017

@名古屋大学

104)Y. Ohki, Y. Araki, M. Tada, and Y. Sakai "Synthesis and Characterization of Bioinspired [Mo2Fe2]-Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N2" Chem. Eur. J. , 23, 13240-13248 (2017). DOI: 10.1002/chem.201702925

103)O. Sekizawa, T. Uruga, N. Ishiguro, H. Matsui, K. Higashi, T. Sakata, Y. Iwasawa, and M. Tada "In-situ X-ray Nano-CT System for Polymer Electrolyte Fuel Cells under Operating Conditions" J. Phys: Conference Series, 849 , 012022 (2017).

102) Y. Takagi, T. Nakamura, L. Yu, S. Chaveanghong, O. Sekizawa, T. Sakata, T. Uruga, M. Tada, Y. Iwasawa, and T. Yokoyama “X-ray Photoelectron Spectroscopy under Real Ambient Pressure Conditions” Appl. Phys. Exp. , 10, 076603 (2017).

101) S. Muratsugu, S. Miyamoto, K. Sakamoto, K. Ichihashi, C. K. Kim, N. Ishiguro, M. Tada "Size Regulation and Stability Enhancement of Pt Nanoparticle Catalyst via Polypyrrole Functionalization of Carbon-Nanotube-Supported Pt Tetranuclear Complex" Langmuir , 33, 10271-10282 (2017). DOI: 10.1021/acs.langmuir.7b02114

100)J. B. Ernst, C. Schwermann, G.-i. Yokota, M. Tada, S. Muratsugu, N. L. Doltsinis, F. Glorius "Molecular Adsorbates Switch on Heterogeneous Catalysis: Induction of Reactivity by N-Heterocyclic Carbenes" J. Am. Chem. Soc., 139 , 9144-9147 (2017). DOI: 10.1021/jacs.7b05112.

99) H. Matsui, N. Ishiguro, T. Uruga, O. Sekizawa, K. Higashi, N. Maejima, M. Tada “Operando 3D Visualization of Migration and Degradation of Pt Cathode Catalyst in a Polymer Electrolyte Fuel Cell” Angew. Chem. Int. Ed. , 56, 9371-9375(2007). DOI: 10.1002/anie.201703940

98) R. Araake, K. Sakadani, M. Tada, Y. Sakai, and Y. Ohki “[Fe4] and [Fe6] Hydride Clusters Supported by Phosphines: Synthesis, Characterization, and Application in N2 Reduction” J. Am. Chem. Soc. 139 , 5596-5606 (2017).

97) Y. Takagi, H. Wang, Y. Uemura, T. Nakamura, L. Yu, O. Sekizawa, T. Uruga, M. Tada, Y. Iwasawa, and T. Yokoyama “In situ Study of Oxidation States of Platinum Nanoparticles on a Polymer Electrolyte Fuel Cell Electrode by Near Ambient Pressure Hard X-ray Photoelectron Spectroscopy” Phys. Chem. Chem. Phys. 19, 6013-6021 (2017).

96)S. Muratsugu, N. Maity, H. Baba, M. Tasaki, and M. Tada “Preparation and Catalytic Performance of a Molecularly Imprinted Pd Complex Catalyst for Suzuki Cross-coupling Reactions” Dalton Trans. , 3125-3134 (2017). (Inside cover).

2016

@名古屋大学

95)Y. Ohki, Y. Shimizu, R. Araake, M. Tada, W. M. C. Sameera, J. Ito, and H. Nishiyama “Co6H8(PiPr3)6: A Cobalt Octahedron with Face-Capping Hydrides” Angew. Chem. Int. Ed. 55, 15821-15825 (2016).

94)N. Ishiguro, S. Kityakarn, O. Sekizawa, T. Uruga, H. Matsui, M. Taguchi, K. Nagasawa, T. Yokoyama, M. Tada “Kinetics and Mechanism of Redox Processes of Pt/C and Pt3Co/C Cathode Electrocatalysts in a Polymer Electrolyte Fuel Cell During an Accelerated Durability Test" J. Phys. Chem. C 120, 19642-19651 (2016).

93)H. Matsui, N. Ishiguro, K. Enomoto, O. Sekizawa, T. Uruga, M. Tada “Imaging of Oxygen Diffusion in Individual Platinum/Ce2Zr2Ox Catalyst Particles During Oxygen Storage and Release" Angew. Chem. Int. Ed. 55, 12022-12025 (2016).

92)J. B. Ernst, S. Muratsugu, F. Wang, M. Tada, F. Glorius “Tunable Heterogeneous Catalysis: N-Heterocyclic Carbenes as Ligands for Supported Heterogeneous Ru/K-Al2O3 Catalysts To Tune Reactivity and Selectivity" J. Am. Chem. Soc. 138, 10718-10721 (2016).

91)O. Sekizawa, T. Uruga, Y. Takagi, K. Nitta, K. Kato, H. Tanida, K. Uesugi, M. Hoshino, E. Ikenaga, K. Takeshita, S. Takahashi, M. Sano, H. Aoyagi, A. Watanabe, N. Nariyama, H. Ohashi, H. Yumoto, T. Koyama, Y. Senba, T. Takeuchi, Y. Furukawa, T. Ohata, T. Matsushita, Y. Ishizawa, T. Kudo, H. Kimura, H. Yamazaki, T. Tanaka, T. Bizen, T. Seike, S. Goto, H. Ohno, M. Takata, H. Kitamura, T. Ishikawa, M. Tada, T. Yokoyama, and Y. Iwasawa “SPring-8 BL36XU: Catalytic Reaction Dynamics for Fuel Cells" J. Phys: Conference Series 712, 012142 (2016).

90)H. Matsui and M. Tada “Imaging Analysis of Heterogeneous Solid Catalyst by Spatially-Resolved XAFS" J. Vac. Soc. Jpn. 59, 307-314 (2016).

2015

@名古屋大学

89) S. Muratsugu, S. Kityakarn, F. Wang, N. Ishiguro, T. Kamachi, K. Yoshizawa, O. Sekizawa, T. Uruga, M. Tada “Formation and Nitrile Hydrogenation Performance of Ru Nanoparticles on a K-doped Al2O3 Surface" Phys. Chem. Chem. Phys. 17, 24791-24802 (2015).

88) T. Sasaki, M. Tada, L. Wang, S. Malwadkar, and Y. Iwasawa “Structure of the Active Pt Cluster Structure and Reaction Pathway of the Selective Synthesis of Phenol from Benzene and Oxygen Regulated with Ammonia on a Pt Cluster/b-Zeolite Catalyst Studied by DFT Calculations" Chem. - Asian J. 17, 2283-2291 (2015).

87) M. Tada, T. Uruga, and Y. Iwasawa, “Key Factors Affecting the Performance and Durability of Cathode Electrocatalysts in Polymer Electrolyte Fuel Cells Characterized by In Situ Time and Spatially Resolved XAFS Techniques” Catal. Lett. 145, 58-70 (2015).

2014

@名古屋大学

86) Y. Takagi, H. Wang, Y. Uemura, E. Ikenaga, O. Sekizawa, T. Uruga, H. Ohashi, Y. Senba, H. Yumoto, H. Yamazaki, S. Goto, M. Tada, Y. Iwasawa, and T. Yokoyama, “In situ Study of an Oxidation Reaction on a Pt/C Electrode by Ambient Pressure Hard X-ray Photoelectron Spectroscopy” App. Phys. Lett. 105, 131692 (2014).

85) N. Ishiguro, S. Kityakarn, O. Sekizawa, T. Uruga, T. Sasabe, K. Nagasawa, T. Yokoyama, and M. Tada, “Rate Enhancements in Structural Transformations of Pt-Co and Pt-Ni Bimetallic Cathode Catalysts in Polymer Electrolyte Fuel Cells Studied by in situ Time-Resolved X-ray Absorption Fine Structure" J. Phys Chem. C 118, 15874-15883 (2014).

84) S. Muratsugu, S. Tajima, and M. Tada “Dispersed RhMo Nanoclusters Prepared from Oxide-Supported Rh2Mo Heterometallic Complexes as Catalysts for Selective Alcohol Oxidation” Chem. Lett. 43, 1321-1323 (2014).

83) N. Ishiguro, T. Uruga, O. Sekizawa, T. Tsuji, M. Suzuki, N. Kawamura, M. Mizumaki, K. Nitta, T. Yokoyama, and M. Tada, “Visualization of the Heterogeneity of Cerium Oxidation States in Single Pt/Ce2Zr2Ox Catalyst Particles by Nano-XAFS” ChemPhysChem 15, 1563-1568 (2014).

82) S. Kityakarn, T. Saida, A. Sode, N. Ishiguro, O. Sekizawa, T. Uruga, K. Nagasawa, T. Yamamoto, T. Yokoyama, and M. Tada, “In Situ Time-resolved XAFS of Transitional States of Pt/C Cathode Electrocatalyst in an MEA during Loading with Transient Voltage” Topics Catal. 57, 903-910 (2014).

2013

@名古屋大学

81) N. Ishiguro, T. Saida, T. Uruga, O. Sekizawa, K. Nagasawa, K. Nitta, T. Yamamoto, S. Ohkoshi, T. Yokoyama, and M. Tada, “Structural Kinetics on a Pt/C Cathode Catalyst with Practical Catalyst Loading in an MEA for PEFC Operating Conditions Studied by In Situ Time-Resolved XAFS” Phys. Chem. Chem. Phys. 15, 18827-18834 (2013).

80) S. Muratsugu, Z. Weng, and M. Tada, “Surface Functionalization of Supported Mn Clusters to Produce Robust Mn Catalysts for Selective Epoxidation” ACS Catal. 3, 2020-2030 (2013).

79) S. Zhang, S. Muratsugu, N. Ishiguro, and M. Tada, “Ceria-doped Ni/SBA-16 Catalysts for Dry Reforming of Methane” ACS Catal. 3, 1855-1864 (2013).

78) S. Muratsugu, M. H. Lim, T. Itoh, W. Thumrongpatanarks, M. Kondo, S. Masaoka, T. S. A. Hor, and M. Tada, “Dispersed Ru Nanoclusters Transformed from a Grafted Trinuclear Ru Complex on SiO2 for Selective Alcohol Oxidation” Dalton Trans. 42, 12611-12619 (2013). [Inside Front Cover].

77) M. Waki, S. Muratsugu, and M. Tada, “Rate Enhancement for Hexose Sugar Oxidation on an Ethynylpyridine-Functionalized Pt/Al2O3 Catalyst with Induced Chirality” Chem. Commun. 49, 7283-7285 (2013). [Inside Back Cover].

2013

@分子科学研究所

75) M. Suzuki, N. Kawamura, M. Mizumaki, Y. Terada, T. Uruga, A. Fujiwara, H. Yamazaki, H. Yumoto, T. Koyama, Y. Sebna, T. Takeuchi, H. Ohashi, N. Nariyama, K. Takeshita, H. Kimura, T. Matsushita, Y. Furukawa, T. Ohata, Y. Kondo, J. Ariake, J. Richter, P. Fons, O. Sekizawa, N. Ishiguro, M. Tada, S. Goto, M. Yamamoto, M. Takata, and T. Ishikawa, “A Hard X-ray Nanospectroscopy Station at SPring-8 BL39XU” J. Phys: Conference Series 430, 012017 (2013).

74) T. Tsuji, T. Uruga, K. Nitta, K. Kawamura, M. Mizumaki, M. Suzuki, O. Sekizawa, N. Ishiguro, M. Tada, H. Ohashi, H. Yamazaki, H. Yumoto, T. Koyama, Y. Senba, T. Takeuchi, Y. Terada, N. Nariyama, K. Takeshita, A. Fujiwara, S. Goto, M. Yamamoto, M. Takata, and T. Ishikawa, “Development of Fast Scanning Microscopic XAFS Measurement System” J. Phys: Conference Series 430, 012019 (2013).

73) O. Sekizawa, T. Uruga, M. Tada, K. Nitta, K. Kato, H. Tanida, K. Takeshita, S. Takahashi, M. Sano, H. Aoyagi, A. Watanabe, N. Nariyama, H. Ohashi, H. Yumoto, T. Koyama, Y. Senba, T. Takeuchi, Y. Furukawa, T. Ohata, T. Matsushita, Y. Ishizawa, T. Kudo, H. Kimura, H. Yamazaki, T. Tanaka, T. Bizen, T. Seike, S. Goto, H. Ohno, M. Takata, H. Kitamura, T. Ishikawa, T. Yokoyama, and Y. Iwasawa, “New XAFS Beamline for Structural and Electronic Dynamics of Nanoparticle Catalysts in Fuel Cells under Operating Conditions” J. Phys: Conference Series 430, 012020 (2013).

72) M. Tada, “Hard X-ray Time-resolved/Space-resolved X-ray Absorption Fine Structure Analysis for Heterogeneous Metal Catalysts” J. Phys. Soc. Jpn. 82, 021013 (2013).

71) L. Wang, S. Yamamoto, S. Malwadkar, S. Nagamatsu, T. Sasaki, K. Hayashizaki, M. Tada, and Y. Iwasawa, “Direct Synthesis of Phenol from Benzene and O2, Regulated by NH3 on Pt/β and Pt-Re/ZSM-5 Catalysts” ChemCatChem 5, 2203-2206 (2013).

70) S. Nagamatsu, T. Arai, M. Yamamoto, T. Ohkura, H. Oyanagi, T. Ishizaka, H. Kawanami, T. Uruga, M. Tada, and Y. Iwasawa, “Potential-Dependent Restructuring and Hysteresis in the Structural and Electronic Transformations of Pt/C, Au(Core)-Pt(Shell)/C, and Pd(Core)-Pt(Shell)/C Cathode Catalysts in Polymer Electrolyte Fuel Cells Characterized by in situ X-ray Absorption Fine Structure” J. Phys. Chem. C 117, 13094-13107 (2013).

69) S. Muratsugu and M. Tada, “Molecularly Imprinted Ru Complex Catalysts Integrated on Oxide Surfaces“ Acc. Chem. Res. 46, 300-311 (2013).

2012

68) S. Muratsugu, Z. Weng, H. Nakai, K. Isobe, T. Sasaki, and M. Tada, “Surface-Assisted Transfer Hydrogenation Catalysis on a γ-Al2O3-Supported Ir Dimer” Phys. Chem. Chem. Phys. 14, 16023-16031 (2012).

67) S. Zhang, S. Muratsugu, N. Ishiguro, S. Ohkoshi, and M. Tada, “Perovskite NaCeTi2O6-Supported Ni Catalysts for CH4 Steam Reforming” ChemCatChem 4, 1783-1790 (2012). [Back Cover of Issue 11].

66) T. Saida, O. Sekizawa, N. Ishiguro, K. Uesugi, M. Hoshina, T. Uruga, S. Ohkoshi, T. Yokoyama, and M. Tada, “4D Visualization of a Cathode Catalyst Layer in a Polymer Electrolyte Fuel Cell by 3D-Laminography-XAFS” Angew. Chem. Int. Ed. 51, 10311-10314 (2012).

65) M. Tada, S. Zhang, S. Malwadkar, N. Ishiguro, J. Soga, Y. Nagai, K. Tezuka, H. Imoto, S. O.-Y.-Matsuo, S. Ohkoshi, and Y. Iwasawa, “The Active Phase of Nickel/Ordered Ce2Zr2Ox Catalysts with a Discontinuous (x = 7-8) in Methane Steam Reforming” Angew. Chem. Int. Ed. 51, 9361-9365 (2012). [HOT PAPER]

64) N. Ishiguro, T. Saida, T. Uruga, O. Sekizawa, S. Nagamatsu, K. Nitta, T. Yamamoto, S. Ohkoshi, Y. Iwasawa, T. Yokoyama, and M. Tada, “Operando Time-resolved X-ray Absorption Fine Structure Study for Surface Events on a Pt3Co/C Cathode Catalyst in a Polymer Electrolyte Fuel Cell during Voltage-Operating Processes” ACS Catal. 2, 1319-1330 (2012).

63) N. Maity, C. Wattanakit, S. Muratsugu, N. Ishiguro, Y. Yang, S. Ohkoshi, and M. Tada, “Sulfoxidation on a SiO2-supported Ru Complex Using O2/Aldehyde System” Dalton Trans. 41, 4558-4565 (2012).

62) Y. Yang, Z. Weng, S. Muratsugu, N. Ishiguro, S. Ohkoshi, and M. Tada, “Preparation and Catalytic Performances of a Molecularly Imprinted Ru-Complex Catalyst with an NH2 Binding Site on a SiO2 Surface” Chem. Eur. J. 18, 1142-1153 (2012).

2011

61) S. Muratsugu, K. Sodeyama, F. Kitamura, S. Tsukada, M. Tada, S. Tsuneyuki, and H. Nishihara, “Normal and Inverted Redox Potentials and Structural Changes Tuned by Medium Effects in [M2Mo(η5-C5Me5)2(S2C6H4),sub2(CO)2] (M: Co, Rh)” Chem. Sci. 2, 1960-1968 (2011).

60) Y. Uemura, Y. Inada, K. K. Bando, T. Sasaki, N. Kamiuchi, K. Eguchi, A. Yagishita, M. Nomura, M. Tada, and Y. Iwasawa, “In situ Time-Resolved XAFS Study on the Structural Transformation and Phase Separation of Pt3Sn and PtSn Alloy Nanoparticles on Carbon in the Oxidation Process” Phys. Chem. Chem. Phys. 13, 15833-15844 (2011).

59) M. Tada, N. Ishiguro, T. Uruga, H. Tanida, Y. Terada, S. Nagamatsu, S. Ohkoshi, and Y. Iwasawa, “μ-XAFS of A Single Particle of A Practical NiOx/Ce2Zr2Oy Catalyst” Phys. Chem. Chem. Phys. 13, 14910-14913 (2011). [Front Cover of Issue 33] (Nature Chem. 4, 873-886 (2012)で紹介)

58) Y. Uemura, Y. Inada, K. K. Bando, T. Sasaki, N. Kamiuchi, K. Eguchi, A. Yagishita, M. Nomura, M. Tada, and Y. Iwasawa, “Core-Shell Phase Separation and Structural Transformation of Pt3Sn Alloy Nanoparticles Supported on γ-Al2O3 in the Reduction and Oxidation Processes Characterized by in-situ Time- Resolved XAFS” J. Phys. Chem. C 115, 5823-5833 (2011).

57) Z. Weng, S. Muratsugu, N. Ishiguro, S. Ohkoshi, and M. Tada, “Preparation of Surface Molecularly Imprinted Ru-Complex Catalysts for Asymmetric Transfer Hydrogenation in Water Media” Dalton Trans. 40, 2338-2347 (2011).

2010

56) M. Tada, “Surface-Mediated Design and Catalytic Properties of Active Metal Complexes for Advanced Catalysis Creation” Bull. Chem. Soc. Jpn. 83, 855-876 (2010) [Award Accounts]. Published online: 2010.7.24, DOI: 10.1246/bcsj.20090336

55) T. Taniike, M. Tada, R. Coquet, Y. Morikawa, T. Sasaki, and Y. Iwasawa, “A Novel Mechanism for Spectator CO-Mediated Reaction with Unique cis-(NO)2 Dimer on a Co2+-Dimer/γ-Al2O3 (110) Model Catalyst: Density Functional Theory Calculations” Catal. Today 154, 118-126 (2010).

54) M. Tada, Y. Uemura, R. Bal, Y. Inada, M. Nomura, and Y. Iwasawa, “In-situ Time-Resolved DXAFS for the Determination of Kinetics of Structural Changes of H-ZSM-5-Supported Active Re-Cluster Catalyst in the Direct Phenol Synthesis from Benzene and O2Phys. Chem. Chem. Phys. 12, 5701-5706 (2010).

53) S. Ichikawa, T. Seki, M. Tada, Y. Iwasawa, and T. Ikariya, “Amorphous Nano-Structured Silicas for High-Performance Carbon Dioxide Confinement” J. Mater. Chem. 20, 3163-3165 (2010).

52) M. Tada, S. Muratsugu, M. Kinoshita, T. Sasaki, and Y. Iwasawa, “Alternative Selective Oxidation Pathways for Aldehyde Oxidation and Alkene Epoxidation on a SiO2-Supported Ru-Monomer Complex Catalyst” J. Am. Chem. Soc. 132, 713-724 (2010).

2009

51) H. Ariga, T. Taniike, H. Morikawa, M. Tada, B. K. Min, K. Watanabe, Y. Matsumoto, S. Ikeda, K. Saiki, and Y. Iwasawa, “Surface-Mediated Visible-Light Photo-Oxidation on Pure TiO2(001)” J. Am. Chem. Soc. 131, 14670-14672 (2009).

50) K. Motokura, S. Tanaka, M. Tada, and Y. Iwasawa, “Bifunctional Heterogeneous Catalysis of Silica-Alumina-Supported Tertiary Amines with Controlled Acid-Base Interactions for Efficient 1,4-Addition Reactions” Chem. Eur. J. 15, 10871-10879 (2009).

49) K. Motokura, M. Tada, and Y. Iwasawa, “Organofunctionalized Catalyst Surfaces Highly Active and Selective for Carbon-Carbon Bond-Forming Reactions” Catal. Today 147, 203-210 (2009).

48) K. Motokura, M. Tada, and Y. Iwasawa, “Layered Materials with Coexisting Acidic and Basic Sites for Catalytic One-Pot Reaction Sequences” J. Am. Chem. Soc. 131, 7944-7945 (2009).

47) T. Sasaki, M. Tada, and Y. Iwasawa, “Density Functional Theory Study on the Re Cluster/HZSM-5 Catalysis for Direct Phenol Synthesis from Benzene and Molecular Oxygen: Active Re Structure and Reaction Mechanism” Topics Catal. 52, 880-887 (2009).

46) K. Motokura, M. Tomita, M. Tada, and Y. Iwasawa, “Michael Reactions Catalyzed by Basic Alkylamines and Dialkylaminopyridine Immobilized on Acidic Silica-Alumina Surfaces” Topics Catal. 52, 579-585 (2009).

2008

45) M. Tada, Y. Akatsuka, Y. Yang, T. Sasaki, M. Kinoshita, K. Motokura, and Y. Iwasawa, “Photoinduced Reversible Structural Transformation and Selective Oxidation Catalysis of Unsaturated Ruthenium Complexes Supported on SiO2Angew. Chem. Int. Ed. 47, 9252-9255 (2008).

44) K. Motokura, M. Tada, and Y. Iwasawa, “Cooperative Catalysis of Primary and Tertiary Amines Immobilized on Oxide Surface for One-Pot C-C Bond Forming Reactions” Angew. Chem. Int. Ed. 47, 9230-9235 (2008).

43) K. Motokura, M. Tada, and Y. Iwasawa, “Acid-Base Bifunctional Catalytic Surfaces for Nucleophilic Addition Reactions” Chem. Asian J. 3, 1230-1236 (2008).

42) M. L. Kantam, U. Pal, B. Sreedhar, S. Bhargava, Y. Iwasawa, M. Tada, and B. M. Choudary, “Aerobic Alcohol Oxidation by Ruthenium Species Stabilized on Nanocrystalline Magnesium Oxide by Basic Ionic Liquids” Adv. Synth. Catal. 350, 1225-1229 (2008).

41) M. Tada, K. Motokura, and Y. Iwasawa, “Conceptual Integration of Homogeneous and Heterogeneous Catalyses” Topic Catal. 48, 32-40 (2008).

40) K. Motokura, M. Tomita, M. Tada, and Y. Iwasawa, “Acid-Base Bifunctional Catalysis of Silica-Alumina-Supported Organic Amines for Carbon-Carbon Bond-Forming Reactions” Chem. Eur. J. 14, 4017-4027 (2008). [Synfact of the Month (Chem. Eur. J.)]

39) T. Sasaki, M. Tada, C. Zhong, T. Kume, and Y. Iwasawa, “Immobilized Metal Ion-Containing Ionic Liquids: Preparation, Structure and Catalytic Performances in Kharasch Addition Reaction and Suzuki Cross-Coupling Reactions” J. Mol. Catal. A: Chem. 279, 200-209 (2008).

38) T. E. Muller, K. Hultzsch, M. Yus, F. Foubelo, and M. Tada, “Hydroamination: Direct Addition of Amines to Alkenes and Alkynes” Chem. Rev. 108, 3795-3892 (2008).

2007

@東京大学

37) M. Tada, and Y. Iwasawa, “Advanced Design of Catalytically Active Reaction Space at Surfaces for Selective Catalysis” Coord. Chem. Rev. 251, 2702-2716 (2007).

36) C. Zhong, T. Sasaki, A. J. Kobayashi, E. Fujiwara, A. Kobayashi, M. Tada, and Y. Iwasawa, “Syntheses, Structures, and Properties of a Series of Metal Ion-Containing Dialkylimidazolium Ionic Liquids” Bull. Chem. Soc. Jpn. 80, 2365-2374 (2007).

35) T. Yamamoto, A. Suzuki, Y. Nagai, T. Tanabe, F. Dong, Y. Inada, M. Nomura, M. Tada, and Y. Iwasawa, “Origin and Dynamics of Oxygen Storage/Release in a Pt/Ordered CeO2-ZrO2 Catalyst Studied by Time-Resolved XAFS Analysis” Angew. Chem. Int. Ed. 46, 9253-9256 (2007).

34) Y. Uemura, T. Taniike, M. Tada, Y. Morikawa, and Y. Iwasawa, “Switchover of Reaction Mechanism for the Catalytic Decomposition of HCOOH on a TiO2(110) Surface” J. Phys. Chem. C 111, 16379-16386 (2007).

33) R. Coquet, M. Tada, and Y. Iwasawa, “Energy-Gaining Formation and Catalytic Behavior of Active Structures in a SiO2-Supported Unsaturated Ru Complex Catalyst for Alkene Epoxidation by DFT Calculations” Phys. Chem. Chem. Phys. 9, 6040-6046 (2007).

32) M. Tada, R. Bal, X. Mu, R. Coquet, S. Namba, and Y. Iwasawa, “Low-Temperature PROX (Preferential Oxidation) on Novel CeO2-Supported Cu-Cluster Catalysts under Fuel-Cell Operating Conditions” Chem. Commun., 4689-4691 (2007).

31) K. Motokura, M. Tada, and Y. Iwasawa, “Heterogeneous Organic Base-Catalyzed Reactions Enhanced by Acid Supports” J. Am. Chem. Soc. 129, 9540-9541 (2007).

30) M. Tada, T. Taniike, and Y. Iwasawa, “Understanding of Novel Surface Events on a Supported Co2+-Ensemble Catalyst Promoted by Gas-Phase Molecules: Increases in the Amount and Reactivity of Adsorbed NO by CO Undetectable at the Catalyst Surface” J. Phys. Chem. C 111, 11663-11675 (2007).

29) M. Tada, R. Bal, T. Sasaki, Y. Uemura, Y. Inada, S. Tanaka, M. Nomura, and Y. Iwasawa, “Novel Re-Cluster/HZSM-5 Catalyst for Highly Selective Phenol Synthesis from Benzene and O2: Performance and Reaction Mechanism” J. Phys. Chem. C 111, 10095-10104 (2007).

28) M. Tada, R. Coquet, J. Yoshida, M. Kinoshita, and Y. Iwasawa, “Selective Formation of a Coordinatively Unsaturated Metal Complex at a Surface: A SiO2-Immobilized, Three-Coordinate Ruthenium Catalyst for Alkene Epoxidation” Angew. Chem. Int. Ed. 46, 7220-7223 (2007).

27) T. Taniike, M. Tada, R. Coquet, Y. Morikawa, T. Sasaki, and Y. Iwasawa, “A New Aspect of Heterogeneous Catalysis: Highly Reactive cis-(NO)2 Dimer and Eley-Rideal Mechanism for NO-CO Reaction on a Co-Dimer/γ-Alumina Catalyst” Chem. Phys. Lett. 443, 66-70 (2007).

26) M. Olea, M. Tada, and Y. Iwasawa, “Temporal Analysis of Products (TAP) Study on Low Temperature Carbon Monoxide Oxidation on Supported Au Catalysts” Topics Catal. 44, 137-143 (2007).

25) M. Tada, S. Murata, T. Asaoka, K. Hiroshima, K. Okumura, H. Tanida, T. Uruga, H. Nakanishi, S. Matsumoto, Y. Inada, M. Nomura, and Y. Iwasawa, “In Situ Time-Resolved Dynamic Surface Events on the Pt/C Cathode in a Fuel Cell under Operando Conditions” Angew. Chem. Int. Ed. 46, 4310-4315 (2007).

24) M. Olea, M. Tada, and Y. Iwasawa, “TAP Study on Carbon Monoxide Oxidation over Supported Gold Catalysts Au/Ti(OH)4* and Au/Fe(OH)3*: Moisture Effect” J. Catal. 248, 60-67 (2007).

23) S. Tanaka, M. Tada, and Y. Iwasawa, “Enantioselectivity Promotion by Achiral Surface Functionalization on SiO2-Supported Cu-Bis(oxazoline) Catalysts for Asymmetric Diels-Alder Reactions” J. Catal. 245, 173-183 (2007).

2006

22) C. Zhong, T. Sasaki, M. Tada, and Y. Iwasawa, “Ni Ion-Containing Ionic Liquid Salt and Ni Ion-Containing Immobilized Ionic Liquid on Silica: Application to Suzuki Cross-Coupling Reactions between Chloroarenes and Arylboronic Acids” J. Catal. 242, 357-364 (2006).

21) M. Tada, R. Bal, and Y. Iwasawa, “Catalyst Design for Selective Oxidation with Molecular Oxygen by Metal-Complex Attachment” Catal. Today 117, 141-147 (2006).

20) M. Tada, R. Bal, S. Namba, and Y. Iwasawa, “Surface-Promoted Novel Synthesis of Supported Metallic Cu Nanoparticles Active for Selective Dehydrogenation of Methanol” Appl. Catal. A: General 307, 78-84 (2006).

19) M. Tada, and Y. Iwasawa, “Advanced Chemical Design with Supported Metal Complexes for Selective Catalysis” Chem. Commun., 2833-2844 (2006). [Invited FEATURE ARTICLE] (Top Ten Access of Chem. Commun. in July 2006)

18) T. Taniike, M. Tada, Y. Morikawa, T. Sasaki, and Y. Iwasawa, “Density Functional Theoretical Calculations for a Co2/γ-Al2O3 Model Catalyst: Structures of the γ-Al2O3 Bulk and Surface and Attachment Sites for Co2+ Ions” J. Phys. Chem. B 110, 4929-4936 (2006).

17) R. Bal, M. Tada, T. Sasaki, and Y. Iwasawa, “Direct Phenol Synthesis by Selective Oxidation of Benzene with Molecular Oxygen on an Interstitial-N/Re Cluster/Zeolite Catalyst” Angew. Chem. Int. Ed. 45, 448-452 (2006). [HOT PAPER]

2005

16) M. Tada, S. Tanaka, and Y. Iwasawa, “Enantioselective Diels-Alder Reaction Promoted by Achiral Functionalization of a SiO2-Supported Cu-BOX [Bis(oxazoline)] Catalyst” Chem. Lett. 34, 1362-1363 (2005).

15) R. Bal, M. Tada, and Y. Iwasawa, “Surfactant-Promoted Novel Reductive Synthesis of Supported Metallic Cu Nanoclusters and Their Catalytic Performances for Selective Dehydrogenation of Methanol” Chem. Commun., 3433-3435 (2005).

14) M. Kotobuki, T. Shido, M. Tada, H. Uchida, H. Yamashita, Y. Iwasawa, and M. Watanabe, “XAFS Characterization of Pt-Fe/Zeolite Catalysts for Preferential Oxidation of CO in Hydrogen Fuel Gases” Catal. Lett. 103, 263-269 (2005).

13) M. Tada, N. Kojima, Y. Izumi, T. Taniike, and Y. Iwasawa, “Chiral Self-Dimerized Vanadium Complexes on a SiO2 Surface for Asymmetric Catalytic Coupling of 2-Naphthol: Structure, Performance, and Mechanism” J. Phys. Chem. B 109, 9905-9916 (2005).

12) T. Sasaki, C. Zhong, M. Tada, and Y. Iwasawa, “Immobilized Metal Ion-Containing Ionic Liquids: Preparation, Structure and Catalytic Performance in Kharasch Addition Reaction” Chem. Commun., 2506-2508 (2005).

11) S. Ichikawa, M. Tada, Y. Iwasawa, and T. Ikariya, “The Role of Carbon Dioxide in Chemoselective Hydrogenation of Halonitroaromatics over Supported Noble Metal Catalysts in Supercritical Carbon Dioxide” Chem. Commun., 924-926 (2005).

10) M. Tada, and Y. Iwasawa, “Chemical Design and In Situ Characterization of Active Surfaces for Selective Catalysis” Annu. Rev. Mater. Res. 35, 397-426 (2005).

2004

9) M. Tada, T. Taniike, L. M. Kantam, and Y. Iwasawa, “Chiral Self-Dimerization of Vanadium Complexes on a SiO2 Surface: The First Heterogeneous Catalyst for Asymmetric 2-Naphthol Coupling” Chem. Commun., 2542-2543 (2004).

8) M. Tada, M. Shimamoto, T. Sasaki, and Y. Iwasawa, “Oxide Surface-Promoted Pd-Complex Catalysis for Intramolecular O-Activated Alkene Hydroamination: Catalyst Preparation, Characterization, and Performance” Chem. Commun., 2562-2563 (2004).

7) M. Tada, T. Sasaki, and Y. Iwasawa, “Design of a Novel Molecular-Imprinted Rh-Amine Complex on SiO2 and Its Shape-Selective Catalysis for α-Methylstyrene Hydrogenation” J. Phys. Chem. B 108, 2918-2930 (2004).

2003

6) M. Tada, and Y. Iwasawa, “Approaches to Design of Active Structures by Attaching and Molecular Imprinting of Metal Complexes on Oxide Surfaces” J. Mol. Catal. A: Chem. 204-205, 27-53 (2003).

5) M. Tada, and Y. Iwasawa, “Design of Molecular-Imprinting Metal-Complex Catalysts” J. Mol. Catal. A: Chem. 199, 115-137 (2003).

2002

4) M. Tada, T. Sasaki, T. Shido, and Y. Iwasawa, “Design, Characterization and Performance of a Molecular Imprinting Rh-Dimer Hydrogenation Catalyst on a SiO2 Surface” Phys. Chem. Chem. Phys. 4, 5899-5909 (2002).

3) M. Tada, T. Sasaki, and Y. Iwasawa, “Novel SiO2-Attached Molecular-Imprinting Rh-Monomer Catalysts for Shape-Selective Hydrogenation of Alkenes; Preparation, Characterization and Performance” Phys. Chem. Chem. Phys. 4, 4561-4574 (2002).

2) M. Tada, T. Sasaki, and Y. Iwasawa, “Performance and Kinetic Behavior of a New SiO2-Attached Molecular-Imprinting Rh-Dimer Catalyst in Size- and Shape-Selective Hydrogenation of Alkenes” J. Catal. 211, 496-510 (2002).

1) A. Suzuki, M. Tada, T. Sasaki, T. Shido, and Y. Iwasawa, “Design of Catalytic Sites at Oxide Surfaces by Metal-Complex Attaching and Molecular Imprinting Techniques” J. Mol. Catal. A: Chem. 182-183, 125-136 (2002).

著書

2017

6) Y. Iwasawa, K. Asakura, M. Tada, XAFS Techniques for Catalysts, Nanomaterials, and Surfaces,Springer,(2017)

2014

6) S. Muratsugu, and M. Tada (Eds. C. Alvarez-Lorenzo), “Molecularly Imprinted Polymers as Catalysts toward Artificial Enzymes” Molecularly Imprinted Polymers: A Handbook for Academia and Industry, iSmithers, in press.

5) 唯美津木, “第11章 触媒の構造変化を捉える” 放射光が拓く化学の現在と未来, 化学同人, p.99-103 (2014).

4) 唯美津木, 笹部崇, “第2章 燃料電池 固体高分子形燃料電池MEAの新しい非破壊3次元XAFS分析法” SPring-8の高輝度放射光を利用したグリーンエネルギー分野における電池材料開発, シーエムシー出版, p.132-137 (2014).

3) M. Tada, and S. Muratsugu (Eds. K. Wilson and A. F. Lee), “Site-Isolated Heterogeneous Catalysts” Heterogeneous Catalysts for Clean Technology, Spectroscopy, Design, and Monitoring, Wiley-VCH, p.173-191 (2014).

2013

2) 唯美津木, “問題3.19 燃料電池” 問題と解説で学ぶ表面科学, 共立出版, p.122 (2013).

1) 唯美津木, 石黒志, “白金合金カソード触媒のin situリアルタイムXAFS構造解析” 次世代燃料電池開発の最前線, シーエムシー出版, p.148-154 (2013).