名古屋大学 大学院理学研究科 物質理学専攻（化学系） 無機化学研究室
Publications
Original Paper
2024
＠Nagoya Univ.
158)T. Moriyama, S. Muratsugu, M. Sato, K. Higuchi, Y. Takagi, M. Tada, "Pt2Gd Alloy Nanoparticles from Organometallic Pt and Gd Com-plexes and Hollow Mesoporous Carbon Spheres: Enhanced Oxy-gen Reduction Reaction Activity and Durability" J, Am. Chem. Soc. Accepted.
157)S. Shirai, S. Muratsugu, H. Matsui, K. Harada, M. Ehara, T. Nakai, M. Tada "Circularly polarized luminescence induction on Tb(III) complex with tris(o-tert-butylaryloxide)-functionalized 1,4,7-triazacyclononane ligand coordinating chiral 1-phenylethylamine" Chem. Commun. 2024, 60, 14180 - 14183.[Selected as a front cover] DOI: 10.1039/D4CC05191B
156)T. Iwano, S. Shirai, C. Chen, Z. Weng, Y. Kikukawa, S. Muratsugu, M. Tada, H. Takatsu, H. Kageyama, S. Uchida, “Incorporation of Poly(vinyl alcohol) into an Inorganic Framework Based on Eu-Bonded Preyssler-Type Phosphotungstate for Enhanced Proton Conduction” ACS Appl. Polym. Mater. 2024, 6, 7929-7931. DOI: 10.1021/acsapm.4c01069
155)M. Liu, Z. Pan, M. Ohwada, R. Tang, H. Matsui, M. Tada, M. Ito, A. Ikura, and H. Nishihara, "Highly Permeable and Regenerative Microhoneycomb Filters” ACS Appl. Mater. Interfaces 2024, 16, 29177-29187. DOI: 10.1021/acsami.4c02697
154)C. Chen, S. Ikemoto, G. Yokota, K. Higuchi, S. Muratsugu, and M. Tada "Low-temperature redox activity and alcohol ammoxidation performance on Cu- and Ru-incorporated ceria catalysts" Phys. Chem. Chem. Phys. 2024, 26, 17979-17990.[Selected as front cover and hot article] DOI: 10.1039/D4CP01432D
153)H. Matsui, T. Ohta, T. Nakamura, T. Uruga, and M. Tada, "In situ 3D X-ray imaging of water distribution in each layer of a membrane electrode assembly of a polymer electrolyte fuel cell" Phys. Chem. Chem. Phys. 2024, 26, 15115-15119. [Selected as Back Cover] DOI: 10.1039/D4CP00728J
152)Y. Matsuoka, Y. Sakai, H. Izu, S. Shimoyama, M. Fujisawa, M. Tada, N. M. Lakshan, W. M. C. Sameera, K. Tanifuji, and Y. Ohki, "Silylation of N2 Catalyzed by Cubic [Mo3S4Ni] Clusters Bearing Mo-Bound Cyclopentadienyl Ligands" Coord. Chem. Res. 2024, 1, 100001. DOI: 10.1016/j.cocr.2024.100001
151)S. Huang, Y. Kimura, T. Nakamura, N. Ishiguro, O. Sekizawa, K. Nitta, T. Uruga, T. Takeuchi, T. Okumura, M. Tada, Y. Uchimoto, and K. Amezawa, "Protracted Relaxation Dynamics of Lithium Heterogeneity in Solid-State Battery Electrodes" J. Phys. Chem. C 2024, 128, 6213-6221. DOI: 10.1021/acs.jpcc.4c00318
150)E. Yamada, H. Sakamoto, H. Matsui, T. Uruga, K. Sugimoto, M.-Q. Ha, H.-C. Dam, R. Matsuda, M. Tada, "Three-Dimensional Visualization of Adsorption Distribution in a Single Crystalline Particle of a Metal-Organic Framework" J. Am. Chem. Soc. 2024, 146, 13, 9181-9190. DOI: 10.1021/jacs.3c14778.
149)H. Matsui, A. Shoji, C. Chen, X. Zhao, T. Uruga, and Mizuki Tada, "Local Structures and Robust Oxygen Reduction Performances of TiN-Supported Bimetallic Pt-Cu Electrocatalysts for Fuel Cell" Catal. Sci. Technol. 2024, 14,1501-1511. DOI: 10.1039/D3CY01438J. (Selected as Front Inside Cover)
148)P. Zatsepin, T. Moriyama, C. Chen, S. Muratsugu, M. Tada, M. Yamashita, "A Vanadium Alumanyl Complex: Synthesis, Characterization, Reactivity, and Application as a Catalyst for C-H Alumanylation of Alkenes" J. Am. Chem. Soc. 2024, 146, 5, 3492-3497 DOI: 10.1021/jacs.3c13418
147)S. Muratsugu, K. Sawaguchi, T. Shiraogawa, S. Chiba, Y. Sakata, S. Shirai, H. Baba, M. Ehara, S. Akine, M. Tada "Induced chirality at surface: Fixation of a dynamic M/P invertible helical Co3 complex on SiO2" Chem. Commun. 2024, 60, 2094-2097. DOI: 10.1039/D3CC05534E
2023
＠Nagoya Univ.
146)Y. Kimura, S. Huang, T. Nakamura, N. Ishiguro, O. Sekizawa, K. Nitta, T. Uruga, T. Takeuchi, T. Okumura, M. Tada, Y. Uchimoto, and K. Amezawa, “5D Analysis of Capacity Degradation in Battery Electrodes Enabled by Operando CT-XANES” Small Methods. 2023, 7, 2300310. DOI: 10.1002/smtd.202300310
145)S. Kurumada, R. Yamanashi, K. Sugita, K. Kubota, H. Ito, S. Ikemoto, C. Chen, T. Moriyama, S. Muratsugu, M. Tada, T. Koitaya, T. Ozaki, M. Yamashita “Mechanochemical Synthesis of Non-Solvated Dialkylalumanyl Anion and XPS Characterization of Al(I) and Al(II) Species” Chem. Eur. J. 2023, e202303073. DOI: 10.1002/chem.202303073
144)H. Matsui, Y. Muramoto, R. Niwa, T. Kakubo, N. Amino, T. Uruga, Minh-Quyet Ha, Duy-Tai Dinh, Hieu-Chi Dam & M. Tada "Machine learning-derived reaction statistics for 3D spectroimaging of copper sulfidation in heterogeneous rubber/brass composites" Communications Materials 2023, 4, 88 DOI：10.1038/s43246-023-00413-z
143)N. Ishiguro, H. Matsui, K. Wakamatsu, Y. Suzuki, O. Sekizawa, K. Nitta, Y. Terada, T. Uruga and M. Tada, "Oxidation and Phase Transfer of Individual Cr-Doped Dendritic FeOx Particles Visualized by Full-field Nano-XAFS Spectroimaging" Phys. Chem. Chem. Phys. 2023, 25, 17197. DOI: 10.1039/D3CP00907F.
142)H. Matsui, K. Sato, N. Isobe, G. Samjeske, T. Uruga, and M. Tada, "Spatial Imaging of Catalyst Poisoning with SO2 on Pt/C PEFC Electrocatalyst by Operando Pt LIII-edge XAFS-CT Imaging" Catal. Sci. Technol. 2023, 13, 4360-4366 DOI: 10.1039/D3CY00241A.(Selected as Front Inside Cover)
2022
＠Nagoya Univ.
141)Y. Ohki, K. Munakata, Y. Matsuoka, R. Hara, M. Kachi, K. Uchida, M. Tada, R. E. Cramer, W. M. C Sameera, T. Takayama, Y. Sakai, S. Kuriyama, Y. Nishibayashi, and K. Tanifuji, “Nitrogen Reduction by the Fe Sites of Synthetic [Mo3S4Fe] Cubes” Nature. 2022, 607, 86-90. DOI: 10.1038/s41586-022-04848-1.
140)K. Tanifuji, Y. Sakai, Y. Matsuoka, M. Tada, W. M. C. Sameera, and Y. Ohki, “CO Binding onto Heterometals of [Mo3S4M] (M = Fe, Co, Ni) Cubes” Bull. Chem. Soc. Jpn. 2022, 95, 1190-1195. DOI: 10.1246/bcsj.20220143.
139)S. Ikemoto, S. Muratsugu, T. Koitaya, Y. Tsuji, M. Das, K. Yoshizawa, F. Glorius, M. Tada “Coordination-Induced Trigger for Activity: N-Heterocyclic Carbene-Decorated Ceria Catalysts Incorporating Cr and Rh with Activity Induction by Surface Adsorption Site Control” J. Am. Chem. Soc. 2023, 145, 3, 1497-1504. DOI: 10.1021/jacs.2c07290.
138)H. Matsui, S. Takao, K. Higashi, T. Kaneko, G. Samjeske, T. Uruga, M. Tada, and Y. Iwasawa, "Operando Imaging of Ce Radical Scavengers in a Practical Polymer Electrolyte Fuel Cell by 3D Fluorescence CT-XAFS and Depth-Profiling Nano-XAFS-SEM/EDS Techniques" ACS Appl. Mater. Interfaces , 2022, 14, 6762-6776. DOI:10.1021/acsami.1c22336
137)H. Matsui, N. Ishiguro, Y. Tan, N. Maejima, Y. Muramoto, T. Uruga, K. Higashi, D.-N. Nguyen, H.-C. Dam, G. Samjeske, M. Tada, "Variation of Local Structure and Reactivity of Pt/C Catalyst for Accelerated Degradation Test of Polymer Electrolyte Fuel Cell Visualized by Operando 3D CT-XAFS Imaging" ChemNanoMat. , 2022, online published. DOI:10.1002/cnma.202200008
2021
＠Nagoya Univ.
136)S. Chaveanghong, T. Nakamura, Y. Takagi, B. Cagnon, T. Uruga, M. Tada, Y. Iwasawa, and T. Yokoyama, “Sulfur Poisoning of Pt and PtCo Anode and Cathode Catalysts in Polymer Electrolyte Fuel Cells Studied by Operando Near Ambient Pressure Hard X-ray Photoelectron Spectroscopy” Phys. Chem. Chem. Phys. , 2021, 23, 3866-3873. DOI: 10.1039/d0cp06020h
135)S. Ikemoto, S. Muratsugu, T. Koitaya, M. Tada, "Chromium Oxides as Structural Modulators of Rhodium Dispersion on Ceria to Generate Active Sites for NO Reduction" ACS Catal. , 2022, 12, 431-441. DOI:10.1021/acscatal.1c03807(Selected as Front Cover)
134) X.-K. Wan, G. Samjeske, H. Matsui, C. Chen, S. Muratsugu, M. Tada “Ultrafine Pt-Ni Nanoparticles in Hollow Porous Carbon Spheres for Remarkable Oxygen Reduction Reaction Catalysis” Dalton Trans. , 2021, 50, 6811-6822. DOI:10.1039/D1DT00647A.(selected as back cover)
2020
＠Nagoya Univ.
133)T. Nakamura, Y. Takagi, S. Chaveanghong, T. Uruga, M. Tada, Y. Iwasawa, and T. Yokoyama, “Quick Operando Ambient Pressure Hard X-ray Photoelectron Spectroscopy for Reaction Kinetic Measurements of Polymer Electrolyte Fuel Cells” J. Phys. Chem., 2020, C 124, 17520-17527, DOI:10.1021/acs.jpcc.0c04871.
132)Y. Kimura, M. Fakkao, T. Nakamura, T. Okumura, N. Ishiguro, O. Sekizawa, K. Nitta, T. Uruga, M. Tada, Y. Uchimoto, and K. Amezawa, “Influence of Active-Material Loading on Electrochemical Reaction in Composite Solid-State Battery Electrodes Revealed by Operando 3D CT-XANES Imaging” ACS Appl. Energy Mater., 2020, 3, 7782-7793. DOI:10.1021/acsaem.0c01186.
131)K. Higashi, S. Takao, G. Samjeske, H. Matsui, M. Tada, T. Uruga, and Y. Iwasawa, "Visualization and Understanding of the Degradation Behaviors of a PEFC Pt/C Cathode Electrocatalyst using a Multi-Analysis System Combining Time-Resolved Quick XAFS, Three-Dimensional XAFS-CT, and Same-View Nano-XAFS/STEM-EDS Techniques". Phys. Chem. Chem. Phys., 2020, 22, 18919-18931. DOI: 10.1039/D0CP01356K.
130)Y. Ohki, K. Ishihara, M. Yaoi, M. Tada, W. M. C. Sameera, and R. E. Cramer, "A Dinuclear Mo2H8 Complex Supported by Bulky C5H2tBu3 Ligands". Chem. Commun., 2020, 56, 8035-8038. DOI: 10.1039/d0cc03274c.
129)H. Matsui, N. Ishiguro, Y. Suzuki, K. Wakamatsu, C. Yamada, K. Sato, N. Maejima, T. Uruga, and M. Tada "Reversible structural transformation and redox properties of Cr-loaded iron oxide dendrites studied by in situ XANES spectroscopy". Phys. Chem. Chem. Phys., 2020, 22, 28093-28099. DOI: 10.1039/D0CP04416D.
128)K. Ichihashi, S. Muratsugu, H. Matsui, K. Higashi, O. Sekizawa, T. Uruga, M. Tada "Oxygen Reduction Reaction Performance Tuning on Pt Nanoparticle/MWCNT Catalysts by Gd Species" J. Phys. Chem. C, 2020, 124, 49, 26925-26936. DOI: 10.1021/acs.jpcc.0c09308.
127) D. Moock, M. P. Wiesenfeldt, M. Freitag, S. Muratsugu, S. Ikemoto, R. Knitsch, J. Schneidewind, W. Baumann, A. H. Schafer, A. Timmer, M. Tada, M. R. Hansen, F. Glorius, "Mechanistic Understanding of the Heterogeneous, Rhodium-Cyclic(Alkyl)(Amino)Carbene-Catalyzed (Fluoro-)Arene Hydrogenation". ACS Catal., 2020, 10, 6309-6317. DOI: 10.1021/acscatal.0c01074.
126) Y.Kimura, A.Tomura, M.Fakkao, T.Nakamura, N.Ishiguro, O.Sekizawa, K.Nitta, T.Uruga, T.Okumura, M.Tada, Y.Uchimoto, K.Amezawa, "3D Operando Imaging and Quantification of Inhomogeneous Electrochemical Reactions in Composite Battery Electrodes". J. Phys. Chem. Lett. , 2020, 11, 3629-3636. DOI: 10.1021/acs.jpclett.0c00876.
125) G.Samjeske, T.Kaneko, T.Gunji, K.Higashi, T.Uruga, M.Tada, Y.Iwasawa, "Feed gas exchange (startup/shutdown) effects on Pt/C cathode electrocatalysis and surface Pt-oxide behavior in polymer electrolyte fuel cells as revealed using in situ real-time XAFS and high-resolution STEM measurements" Phys. Chem. Chem. Phys., 2020, 22, 9424-9437. DOI: 10.1039/c9cp06895c.
124) S. Muratsugu, S. Shirai, M. Tada "Recent Progress in Molecularly Imprinted Approach for Catalysis" Tetrahedron Lett., 2020, 61,151603. DOI: 10.1016/j.tetlet.2020.151603. (Invited Digest)
123)S. Akiyama, S. Ikemoto, S. Muratsugu, M. Tada, M. Yamashita "Copper Complexes Bearing a Dianionic Diborane(4) Ligand: Synthesis and Evaluation of the Donor Property" Organometallics, 2020, 39, 500-514. DOI: 10.1021/acs.organomet.0c00027.
2019
＠Nagoya Univ.
122) S. Ikemoto, X. Huang, S. Muratsugu, S. Nagase, T. Koitaya, H. Matsui, G. Yokota, T. Sudoh, A. Hashimoto, Y. Tan, S. Yamamoto, J. Tang, I. Matsuda, J. Yoshinobu, T. Yokoyama, S. Kusaka, R. Matsuda, and M. Tada “Reversible Low-Temperature Redox Activity and Selective Oxidation Catalysis Derived from Concerted Activation of Multiple Metal Species on Cr and Rh-Incorporated Ceria Catalysts” Phys. Chem. Chem. Phys.,31, 18844-18853 (2019). DOI:10.1039/C9CP04625A.
121) S. Morisako, S. Watanabe, S. Ikemoto, S. Muratsugu, M. Tada, and M. Yamashita “Synthesis of A Pincer-Ir(V) Complex with A Base-Free Alumanyl Ligand and Its Application toward Dehydrogenation of Alkanes” Angew. Chem. Int. Ed., 58, 15031-15035 (2019). DOI: 10.1002/anie.201909009
120) Y. Tan, H. Matsui, N. Ishiguro, T. Uruga, D. N. Nguyen, O. Sekizawa, T. Sakata, N. Maejima, K. Higashi, H. C. Dam, and M. Tada “PtCo/C Cathode Catalyst Degradation in a Polymer Electrolyte Fuel Cell Investigated by an Infographic Approach Combining Three-Dimensional Spectroimaging and Unsupervised Learning” J. Phys. Chem. C, 123, 31, 18844-18853 (2019).[Supplementary Cover of JPCC] DOI: 10.1021/acs.jpcc.9b05005
119) T. Uruga, M. Tada, O. Sekizawa, Y. Takagi, T. Yokoyama, and Y. Iwasawa “SPring-8 BL36XU: Synchrotron Radiation X-ray-based Multi-analytical Beamline for Polymer Electrolyte Fuel Cells under Operating Conditions” Chem. Rec. 19, 1444-1456 (2019). [Invited personal accounts] DOI: 10.1002/tcr.201800193,
118) H. Matsui, N. Maejima, N. Ishiguro, Y. Tan, T. Uruga, O. Sekizawa, T. Sakata, and M. Tada “Operando XAFS Imaging of Distribution of Pt Cathode Catalysts in PEFC MEA” Chem. Rec. 19, 1380-1392 (2019). [Invited personal accounts] DOI: 10.1002/tcr.201800123
117)M. Hirose, N. Ishiguro, K. Shimomura, D. N. Nguyen, H. Matsui, H. C. Dam, M. Tada, and Y. Takahashi “Oxygen-Diffusion-Driven Oxidation Behavior and Tracking Areas Visualized by X-ray Spectro-Ptychography with Unsupervised Learning” Commun. Chem. 2, 50 (2019). DOI: 10.1038/s42004-019-0147-y
116)Y. Ohki, R. Hara, K. Munakata, M. Tada, T. Takayama, Y. Sakai, and R. Cramer “Synthesis of [Mo3S4] Clusters from Half-Sandwich Mo(V) Chlorides and Their Application as Platforms for [Mo3S4Fe] Cubes” Inorg. Chem. 58, 5230-5240 (2019). DOI: 10.1021/acs.inorgchem.9b00309
115)K. Ichihashi, S. Muratsugu, S. Miyamoto, K. Sakamoto, N. Ishiguro, M. Tada
"Enhanced Oxygen Reduction Reaction Performance of Size-controlled Pt Nanoparticles on Polypyrrole-Functionalized Carbon Nanotubes"
Dalton Trans., 48, 7130 - 7137 (2019). [Inside Front Cover ] DOI: 10.1039/C9DT00158A
114)L. Yu, Y. Takagi, T. Nakamura, T. Sakata, T. Uruga, M. Tada, Y. Iwasawa, S. Masaoka, and T. Yokoyama “Operando Observation of Sulfur Species Poisoning Polymer Electrolyte Fuel Cell Studied by Near Ambient Pressure Hard X-ray Photoelectron Spectroscopy” J. Phys. Chem. C 123, 603-611 (2019). 10.1021/acs.jpcc.8b10611
2018
＠Nagoya Univ.
113)Y. Ohki, K. Uchida, R. Hara, M. Kachi, M. Fujisawa, M. Tada, Y. Sakai, W. M. C. Sammera, "Cubane-Type [Mo3S4M] Clusters with First-Row Group 4-10 Transition-Metal Halides Supported by C5Me5 Ligands on Molybdenum" Chem. Eur. J. , 24, 17138-17147 (2018). DOI: 10.1002/chem.201804083
112)Y. Ohki, K. Uchida, M. Tada, R. E. Cramer, T. Ogura, and T. Ohta "N2 Activation on a Molybdenum-Titanium-Sulfur Cluster" Nature Commun. , 9, 3200 (2018). DOI: 10.1038/s41467-018-05630-6
111)Y. Tan, H. Matsui, N. Ishiguro, and M. Tada "Three-dimensional XAFS Imaging of Polymer Electrolyte Fuel Cell Cathode Catalysts in Membrane Electrode Assembly" Acc. Mater. Surf. Res. 3, 165-171 (2018). [Invited]
110)P. Tegeder, M. Freitag, K. M. Chepiga, S. Muratsugu, N. Moller, S. Lamping, M. Tada, F. Glorius, B. J. Ravoo "N-Heterocyclic Carbene-Modified AuPd Alloy Nanoparticles and their Application as Biomimetic and Heterogeneous Catalysts" Chem. Eur. J. , 24, 18682-18688 (2018). DOI:10.1002/chem.201803274
109)S. Ozawa, H. Matsui, N. Ishiguro, Y. Tan, N. Maejima, M. Taguchi, T. Uruga, O. Sekizawa, T. Sakata, K. Nagasawa, K. Higashi, and M. Tada "Operando Time-Resolved XAFS Study for Pt Oxidation Kinetics on Pt/C and Pt3Co/C Cathode Catalysts by PEFC Voltage Operation Synchronized with Rapid O2 Exposure" J. Phys. Chem. , 122, 14511-14517 (2018). DOI: 10.1021/acs.jpcc.8b02541
108)N. Ishiguro and M. Tada "Structural Kinetics of Cathode Events on Polymer Electrolyte Fuel Cell Catalysts Studied by Operando Time-resolved XAFS" Catal. Lett. , 148, 1597-1609 (2018). DOI: 10.1007/s10562-018-2383-7
107)S. Muratsugu, H. Baba, T. Tanimoto, K. Sawaguchi, S. Ikemoto, M. Tasaki, Y. Terao, M. Tada “Chemoselective Epoxidation of Cholesterol Derivatives on a Surface-Designed Molecularly Imprinted Ru-Porphyrin Catalyst” Chem. Commun. , 54, 5114-5117 (2018). DOI: 10.1039/C8CC00896E
106)S. Muratsugu, A. Yamaguchi, G.-i. Yokota, T. Maeno, M. Tada “Tuning the Structure and Catalytic Activity of Ru Nanoparticle Catalysts by Single 3d Transition-metal Atoms in Ru12-Metalloporphyrin Precursors” Chem. Commun. , 54, 4842-4845 (2018). DOI: 10.1039/C7CC09862F
105)M. Hirose, N. Ishiguro, K. Shimomura, D. Burdet, H. Matsui, M. Tada, Y. Takahashi "Visualization of Heterogeneous Oxygen Storage Behavior in Platinum-Supported Cerium-Zirconium Oxide Three-Way Catalyst Particles by Hard X-ray Spectro-Ptychography" Angew. Chem. Int. Ed. , 57, 1474 (2018). DOI: 10.1002/anie.201710798
2017
＠Nagoya Univ.
104)Y. Ohki, Y. Araki, M. Tada, and Y. Sakai "Synthesis and Characterization of Bioinspired [Mo2Fe2]-Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N2" Chem. Eur. J. , 23, 13240-13248 (2017). DOI: 10.1002/chem.201702925
103)O. Sekizawa, T. Uruga, N. Ishiguro, H. Matsui, K. Higashi, T. Sakata, Y. Iwasawa, and M. Tada "In-situ X-ray Nano-CT System for Polymer Electrolyte Fuel Cells under Operating Conditions" J. Phys: Conference Series, 849 , 012022 (2017).
102) Y. Takagi, T. Nakamura, L. Yu, S. Chaveanghong, O. Sekizawa, T. Sakata, T. Uruga, M. Tada, Y. Iwasawa, and T. Yokoyama “X-ray Photoelectron Spectroscopy under Real Ambient Pressure Conditions” Appl. Phys. Exp. , 10, 076603 (2017).
101) S. Muratsugu, S. Miyamoto, K. Sakamoto, K. Ichihashi, C. K. Kim, N. Ishiguro, M. Tada "Size Regulation and Stability Enhancement of Pt Nanoparticle Catalyst via Polypyrrole Functionalization of Carbon-Nanotube-Supported Pt Tetranuclear Complex" Langmuir , 33, 10271-10282 (2017). DOI: 10.1021/acs.langmuir.7b02114
100)J. B. Ernst, C. Schwermann, G.-i. Yokota, M. Tada, S. Muratsugu, N. L. Doltsinis, F. Glorius "Molecular Adsorbates Switch on Heterogeneous Catalysis: Induction of Reactivity by N-Heterocyclic Carbenes" J. Am. Chem. Soc., 139 , 9144-9147 (2017). DOI: 10.1021/jacs.7b05112.
99) H. Matsui, N. Ishiguro, T. Uruga, O. Sekizawa, K. Higashi, N. Maejima, M. Tada “Operando 3D Visualization of Migration and Degradation of Pt Cathode Catalyst in a Polymer Electrolyte Fuel Cell” Angew. Chem. Int. Ed. , 56, 9371-9375(2007). DOI: 10.1002/anie.201703940
98) R. Araake, K. Sakadani, M. Tada, Y. Sakai, and Y. Ohki “[Fe4] and [Fe6] Hydride Clusters Supported by Phosphines: Synthesis, Characterization, and Application in N2 Reduction” J. Am. Chem. Soc. 139 , 5596-5606 (2017).
97) Y. Takagi, H. Wang, Y. Uemura, T. Nakamura, L. Yu, O. Sekizawa, T. Uruga, M. Tada, Y. Iwasawa, and T. Yokoyama “In situ Study of Oxidation States of Platinum Nanoparticles on a Polymer Electrolyte Fuel Cell Electrode by Near Ambient Pressure Hard X-ray Photoelectron Spectroscopy” Phys. Chem. Chem. Phys. 19, 6013-6021 (2017).
96)S. Muratsugu, N. Maity, H. Baba, M. Tasaki, and M. Tada “Preparation and Catalytic Performance of a Molecularly Imprinted Pd Complex Catalyst for Suzuki Cross-coupling Reactions” Dalton Trans. , 3125-3134 (2017). (Inside cover).
2016
＠Nagoya Univ.
95)Y. Ohki, Y. Shimizu, R. Araake, M. Tada, W. M. C. Sameera, J. Ito, and H. Nishiyama “Co6H8(PiPr3)6: A Cobalt Octahedron with Face-Capping Hydrides” Angew. Chem. Int. Ed. 55, 15821-15825 (2016).
94)N. Ishiguro, S. Kityakarn, O. Sekizawa, T. Uruga, H. Matsui, M. Taguchi, K. Nagasawa, T. Yokoyama, M. Tada “Kinetics and Mechanism of Redox Processes of Pt/C and Pt3Co/C Cathode Electrocatalysts in a Polymer Electrolyte Fuel Cell During an Accelerated Durability Test" J. Phys. Chem. C 120, 19642-19651 (2016).
93)H. Matsui, N. Ishiguro, K. Enomoto, O. Sekizawa, T. Uruga, M. Tada “Imaging of Oxygen Diffusion in Individual Platinum/Ce2Zr2Ox Catalyst Particles During Oxygen Storage and Release" Angew. Chem. Int. Ed. 55, 12022-12025 (2016).
92)J. B. Ernst, S. Muratsugu, F. Wang, M. Tada, F. Glorius “Tunable Heterogeneous Catalysis: N-Heterocyclic Carbenes as Ligands for Supported Heterogeneous Ru/K-Al2O3 Catalysts To Tune Reactivity and Selectivity" J. Am. Chem. Soc. 138, 10718-10721 (2016).
91)O. Sekizawa, T. Uruga, Y. Takagi, K. Nitta, K. Kato, H. Tanida, K. Uesugi, M. Hoshino, E. Ikenaga, K. Takeshita, S. Takahashi, M. Sano, H. Aoyagi, A. Watanabe, N. Nariyama, H. Ohashi, H. Yumoto, T. Koyama, Y. Senba, T. Takeuchi, Y. Furukawa, T. Ohata, T. Matsushita, Y. Ishizawa, T. Kudo, H. Kimura, H. Yamazaki, T. Tanaka, T. Bizen, T. Seike, S. Goto, H. Ohno, M. Takata, H. Kitamura, T. Ishikawa, M. Tada, T. Yokoyama, and Y. Iwasawa “SPring-8 BL36XU: Catalytic Reaction Dynamics for Fuel Cells" J. Phys: Conference Series 712, 012142 (2016).
90)H. Matsui and M. Tada “Imaging Analysis of Heterogeneous Solid Catalyst by Spatially-Resolved XAFS" J. Vac. Soc. Jpn. 59, 307-314 (2016).
2015
＠Nagoya Univ.
89) S. Muratsugu, S. Kityakarn, F. Wang, N. Ishiguro, T. Kamachi, K. Yoshizawa, O. Sekizawa, T. Uruga, M. Tada “Formation and Nitrile Hydrogenation Performance of Ru Nanoparticles on a K-doped Al2O3 Surface" Phys. Chem. Chem. Phys. 17, 24791-24802 (2015).
88) T. Sasaki, M. Tada, L. Wang, S. Malwadkar, and Y. Iwasawa “Structure of the Active Pt Cluster Structure and Reaction Pathway of the Selective Synthesis of Phenol from Benzene and Oxygen Regulated with Ammonia on a Pt Cluster/b-Zeolite Catalyst Studied by DFT Calculations" Chem. - Asian J. 17, 2283-2291 (2015).
87) M. Tada, T. Uruga, and Y. Iwasawa, “Key Factors Affecting the Performance and Durability of Cathode Electrocatalysts in Polymer Electrolyte Fuel Cells Characterized by In Situ Time and Spatially Resolved XAFS Techniques” Catal. Lett. 145, 58-70 (2015).
2014
＠Nagoya Univ.
86) Y. Takagi, H. Wang, Y. Uemura, E. Ikenaga, O. Sekizawa, T. Uruga, H. Ohashi, Y. Senba, H. Yumoto, H. Yamazaki, S. Goto, M. Tada, Y. Iwasawa, and T. Yokoyama, “In situ Study of an Oxidation Reaction on a Pt/C Electrode by Ambient Pressure Hard X-ray Photoelectron Spectroscopy” App. Phys. Lett. 105, 131692 (2014).
85) N. Ishiguro, S. Kityakarn, O. Sekizawa, T. Uruga, T. Sasabe, K. Nagasawa, T. Yokoyama, and M. Tada, “Rate Enhancements in Structural Transformations of Pt-Co and Pt-Ni Bimetallic Cathode Catalysts in Polymer Electrolyte Fuel Cells Studied by in situ Time-Resolved X-ray Absorption Fine Structure" J. Phys Chem. C 118, 15874-15883 (2014).
84) S. Muratsugu, S. Tajima, and M. Tada “Dispersed RhMo Nanoclusters Prepared from Oxide-Supported Rh2Mo Heterometallic Complexes as Catalysts for Selective Alcohol Oxidation” Chem. Lett. 43, 1321-1323 (2014).
83) N. Ishiguro, T. Uruga, O. Sekizawa, T. Tsuji, M. Suzuki, N. Kawamura, M. Mizumaki, K. Nitta, T. Yokoyama, and M. Tada, “Visualization of the Heterogeneity of Cerium Oxidation States in Single Pt/Ce2Zr2Ox Catalyst Particles by Nano-XAFS” ChemPhysChem 15, 1563-1568 (2014).
82) S. Kityakarn, T. Saida, A. Sode, N. Ishiguro, O. Sekizawa, T. Uruga, K. Nagasawa, T. Yamamoto, T. Yokoyama, and M. Tada, “In Situ Time-resolved XAFS of Transitional States of Pt/C Cathode Electrocatalyst in an MEA during Loading with Transient Voltage” Topics Catal. 57, 903-910 (2014).
2013
＠Nagoya Univ.
81) N. Ishiguro, T. Saida, T. Uruga, O. Sekizawa, K. Nagasawa, K. Nitta, T. Yamamoto, S. Ohkoshi, T. Yokoyama, and M. Tada, “Structural Kinetics on a Pt/C Cathode Catalyst with Practical Catalyst Loading in an MEA for PEFC Operating Conditions Studied by In Situ Time-Resolved XAFS” Phys. Chem. Chem. Phys. 15, 18827-18834 (2013).
80) S. Muratsugu, Z. Weng, and M. Tada, “Surface Functionalization of Supported Mn Clusters to Produce Robust Mn Catalysts for Selective Epoxidation” ACS Catal. 3, 2020-2030 (2013).
79) S. Zhang, S. Muratsugu, N. Ishiguro, and M. Tada, “Ceria-doped Ni/SBA-16 Catalysts for Dry Reforming of Methane” ACS Catal. 3, 1855-1864 (2013).
78) S. Muratsugu, M. H. Lim, T. Itoh, W. Thumrongpatanarks, M. Kondo, S. Masaoka, T. S. A. Hor, and M. Tada, “Dispersed Ru Nanoclusters Transformed from a Grafted Trinuclear Ru Complex on SiO2 for Selective Alcohol Oxidation” Dalton Trans. 42, 12611-12619 (2013). [Inside Front Cover].
77) M. Waki, S. Muratsugu, and M. Tada, “Rate Enhancement for Hexose Sugar Oxidation on an Ethynylpyridine-Functionalized Pt/Al2O3 Catalyst with Induced Chirality” Chem. Commun. 49, 7283-7285 (2013). [Inside Back Cover].
2013
＠Inst. Molecular Science
75) M. Suzuki, N. Kawamura, M. Mizumaki, Y. Terada, T. Uruga, A. Fujiwara, H. Yamazaki, H. Yumoto, T. Koyama, Y. Sebna, T. Takeuchi, H. Ohashi, N. Nariyama, K. Takeshita, H. Kimura, T. Matsushita, Y. Furukawa, T. Ohata, Y. Kondo, J. Ariake, J. Richter, P. Fons, O. Sekizawa, N. Ishiguro, M. Tada, S. Goto, M. Yamamoto, M. Takata, and T. Ishikawa, “A Hard X-ray Nanospectroscopy Station at SPring-8 BL39XU” J. Phys: Conference Series 430, 012017 (2013).
74) T. Tsuji, T. Uruga, K. Nitta, K. Kawamura, M. Mizumaki, M. Suzuki, O. Sekizawa, N. Ishiguro, M. Tada, H. Ohashi, H. Yamazaki, H. Yumoto, T. Koyama, Y. Senba, T. Takeuchi, Y. Terada, N. Nariyama, K. Takeshita, A. Fujiwara, S. Goto, M. Yamamoto, M. Takata, and T. Ishikawa, “Development of Fast Scanning Microscopic XAFS Measurement System” J. Phys: Conference Series 430, 012019 (2013).
73) O. Sekizawa, T. Uruga, M. Tada, K. Nitta, K. Kato, H. Tanida, K. Takeshita, S. Takahashi, M. Sano, H. Aoyagi, A. Watanabe, N. Nariyama, H. Ohashi, H. Yumoto, T. Koyama, Y. Senba, T. Takeuchi, Y. Furukawa, T. Ohata, T. Matsushita, Y. Ishizawa, T. Kudo, H. Kimura, H. Yamazaki, T. Tanaka, T. Bizen, T. Seike, S. Goto, H. Ohno, M. Takata, H. Kitamura, T. Ishikawa, T. Yokoyama, and Y. Iwasawa, “New XAFS Beamline for Structural and Electronic Dynamics of Nanoparticle Catalysts in Fuel Cells under Operating Conditions” J. Phys: Conference Series 430, 012020 (2013).
72) M. Tada, “Hard X-ray Time-resolved/Space-resolved X-ray Absorption Fine Structure Analysis for Heterogeneous Metal Catalysts” J. Phys. Soc. Jpn. 82, 021013 (2013).
71) L. Wang, S. Yamamoto, S. Malwadkar, S. Nagamatsu, T. Sasaki, K. Hayashizaki, M. Tada, and Y. Iwasawa, “Direct Synthesis of Phenol from Benzene and O2, Regulated by NH3 on Pt/β and Pt-Re/ZSM-5 Catalysts” ChemCatChem 5, 2203-2206 (2013).
70) S. Nagamatsu, T. Arai, M. Yamamoto, T. Ohkura, H. Oyanagi, T. Ishizaka, H. Kawanami, T. Uruga, M. Tada, and Y. Iwasawa, “Potential-Dependent Restructuring and Hysteresis in the Structural and Electronic Transformations of Pt/C, Au(Core)-Pt(Shell)/C, and Pd(Core)-Pt(Shell)/C Cathode Catalysts in Polymer Electrolyte Fuel Cells Characterized by in situ X-ray Absorption Fine Structure” J. Phys. Chem. C 117, 13094-13107 (2013).
69) S. Muratsugu and M. Tada, “Molecularly Imprinted Ru Complex Catalysts Integrated on Oxide Surfaces“ Acc. Chem. Res. 46, 300-311 (2013).
2012
68) S. Muratsugu, Z. Weng, H. Nakai, K. Isobe, T. Sasaki, and M. Tada, “Surface-Assisted Transfer Hydrogenation Catalysis on a γ-Al2O3-Supported Ir Dimer” Phys. Chem. Chem. Phys. 14, 16023-16031 (2012).
67) S. Zhang, S. Muratsugu, N. Ishiguro, S. Ohkoshi, and M. Tada, “Perovskite NaCeTi2O6-Supported Ni Catalysts for CH4 Steam Reforming” ChemCatChem 4, 1783-1790 (2012). [Back Cover of Issue 11].
66) T. Saida, O. Sekizawa, N. Ishiguro, K. Uesugi, M. Hoshina, T. Uruga, S. Ohkoshi, T. Yokoyama, and M. Tada, “4D Visualization of a Cathode Catalyst Layer in a Polymer Electrolyte Fuel Cell by 3D-Laminography-XAFS” Angew. Chem. Int. Ed. 51, 10311-10314 (2012).
65) M. Tada, S. Zhang, S. Malwadkar, N. Ishiguro, J. Soga, Y. Nagai, K. Tezuka, H. Imoto, S. O.-Y.-Matsuo, S. Ohkoshi, and Y. Iwasawa, “The Active Phase of Nickel/Ordered Ce2Zr2Ox Catalysts with a Discontinuous (x = 7-8) in Methane Steam Reforming” Angew. Chem. Int. Ed. 51, 9361-9365 (2012). [HOT PAPER]
64) N. Ishiguro, T. Saida, T. Uruga, O. Sekizawa, S. Nagamatsu, K. Nitta, T. Yamamoto, S. Ohkoshi, Y. Iwasawa, T. Yokoyama, and M. Tada, “Operando Time-resolved X-ray Absorption Fine Structure Study for Surface Events on a Pt3Co/C Cathode Catalyst in a Polymer Electrolyte Fuel Cell during Voltage-Operating Processes” ACS Catal. 2, 1319-1330 (2012).
63) N. Maity, C. Wattanakit, S. Muratsugu, N. Ishiguro, Y. Yang, S. Ohkoshi, and M. Tada, “Sulfoxidation on a SiO2-supported Ru Complex Using O2/Aldehyde System” Dalton Trans. 41, 4558-4565 (2012).
62) Y. Yang, Z. Weng, S. Muratsugu, N. Ishiguro, S. Ohkoshi, and M. Tada, “Preparation and Catalytic Performances of a Molecularly Imprinted Ru-Complex Catalyst with an NH2 Binding Site on a SiO2 Surface” Chem. Eur. J. 18, 1142-1153 (2012).
2011
61) S. Muratsugu, K. Sodeyama, F. Kitamura, S. Tsukada, M. Tada, S. Tsuneyuki, and H. Nishihara, “Normal and Inverted Redox Potentials and Structural Changes Tuned by Medium Effects in [M2Mo(η5-C5Me5)2(S2C6H4),sub2(CO)2] (M: Co, Rh)” Chem. Sci. 2, 1960-1968 (2011).
60) Y. Uemura, Y. Inada, K. K. Bando, T. Sasaki, N. Kamiuchi, K. Eguchi, A. Yagishita, M. Nomura, M. Tada, and Y. Iwasawa, “In situ Time-Resolved XAFS Study on the Structural Transformation and Phase Separation of Pt3Sn and PtSn Alloy Nanoparticles on Carbon in the Oxidation Process” Phys. Chem. Chem. Phys. 13, 15833-15844 (2011).
59) M. Tada, N. Ishiguro, T. Uruga, H. Tanida, Y. Terada, S. Nagamatsu, S. Ohkoshi, and Y. Iwasawa, “μ-XAFS of A Single Particle of A Practical NiOx/Ce2Zr2Oy Catalyst” Phys. Chem. Chem. Phys. 13, 14910-14913 (2011). [Front Cover of Issue 33] (Nature Chem. 4, 873-886 (2012)で紹介)
58) Y. Uemura, Y. Inada, K. K. Bando, T. Sasaki, N. Kamiuchi, K. Eguchi, A. Yagishita, M. Nomura, M. Tada, and Y. Iwasawa, “Core-Shell Phase Separation and Structural Transformation of Pt3Sn Alloy Nanoparticles Supported on γ-Al2O3 in the Reduction and Oxidation Processes Characterized by in-situ Time- Resolved XAFS” J. Phys. Chem. C 115, 5823-5833 (2011).
57) Z. Weng, S. Muratsugu, N. Ishiguro, S. Ohkoshi, and M. Tada, “Preparation of Surface Molecularly Imprinted Ru-Complex Catalysts for Asymmetric Transfer Hydrogenation in Water Media” Dalton Trans. 40, 2338-2347 (2011).
2010
56) M. Tada, “Surface-Mediated Design and Catalytic Properties of Active Metal Complexes for Advanced Catalysis Creation” Bull. Chem. Soc. Jpn. 83, 855-876 (2010) [Award Accounts]. Published online: 2010.7.24, DOI: 10.1246/bcsj.20090336
55) T. Taniike, M. Tada, R. Coquet, Y. Morikawa, T. Sasaki, and Y. Iwasawa, “A Novel Mechanism for Spectator CO-Mediated Reaction with Unique cis-(NO)2 Dimer on a Co2+-Dimer/γ-Al2O3 (110) Model Catalyst: Density Functional Theory Calculations” Catal. Today 154, 118-126 (2010).
54) M. Tada, Y. Uemura, R. Bal, Y. Inada, M. Nomura, and Y. Iwasawa, “In-situ Time-Resolved DXAFS for the Determination of Kinetics of Structural Changes of H-ZSM-5-Supported Active Re-Cluster Catalyst in the Direct Phenol Synthesis from Benzene and O2” Phys. Chem. Chem. Phys. 12, 5701-5706 (2010).
53) S. Ichikawa, T. Seki, M. Tada, Y. Iwasawa, and T. Ikariya, “Amorphous Nano-Structured Silicas for High-Performance Carbon Dioxide Confinement” J. Mater. Chem. 20, 3163-3165 (2010).
52) M. Tada, S. Muratsugu, M. Kinoshita, T. Sasaki, and Y. Iwasawa, “Alternative Selective Oxidation Pathways for Aldehyde Oxidation and Alkene Epoxidation on a SiO2-Supported Ru-Monomer Complex Catalyst” J. Am. Chem. Soc. 132, 713-724 (2010).
2009
51) H. Ariga, T. Taniike, H. Morikawa, M. Tada, B. K. Min, K. Watanabe, Y. Matsumoto, S. Ikeda, K. Saiki, and Y. Iwasawa, “Surface-Mediated Visible-Light Photo-Oxidation on Pure TiO2(001)” J. Am. Chem. Soc. 131, 14670-14672 (2009).
50) K. Motokura, S. Tanaka, M. Tada, and Y. Iwasawa, “Bifunctional Heterogeneous Catalysis of Silica-Alumina-Supported Tertiary Amines with Controlled Acid-Base Interactions for Efficient 1,4-Addition Reactions” Chem. Eur. J. 15, 10871-10879 (2009).
49) K. Motokura, M. Tada, and Y. Iwasawa, “Organofunctionalized Catalyst Surfaces Highly Active and Selective for Carbon-Carbon Bond-Forming Reactions” Catal. Today 147, 203-210 (2009).
48) K. Motokura, M. Tada, and Y. Iwasawa, “Layered Materials with Coexisting Acidic and Basic Sites for Catalytic One-Pot Reaction Sequences” J. Am. Chem. Soc. 131, 7944-7945 (2009).
47) T. Sasaki, M. Tada, and Y. Iwasawa, “Density Functional Theory Study on the Re Cluster/HZSM-5 Catalysis for Direct Phenol Synthesis from Benzene and Molecular Oxygen: Active Re Structure and Reaction Mechanism” Topics Catal. 52, 880-887 (2009).
46) K. Motokura, M. Tomita, M. Tada, and Y. Iwasawa, “Michael Reactions Catalyzed by Basic Alkylamines and Dialkylaminopyridine Immobilized on Acidic Silica-Alumina Surfaces” Topics Catal. 52, 579-585 (2009).
2008
45) M. Tada, Y. Akatsuka, Y. Yang, T. Sasaki, M. Kinoshita, K. Motokura, and Y. Iwasawa, “Photoinduced Reversible Structural Transformation and Selective Oxidation Catalysis of Unsaturated Ruthenium Complexes Supported on SiO2” Angew. Chem. Int. Ed. 47, 9252-9255 (2008).
44) K. Motokura, M. Tada, and Y. Iwasawa, “Cooperative Catalysis of Primary and Tertiary Amines Immobilized on Oxide Surface for One-Pot C-C Bond Forming Reactions” Angew. Chem. Int. Ed. 47, 9230-9235 (2008).
43) K. Motokura, M. Tada, and Y. Iwasawa, “Acid-Base Bifunctional Catalytic Surfaces for Nucleophilic Addition Reactions” Chem. Asian J. 3, 1230-1236 (2008).
42) M. L. Kantam, U. Pal, B. Sreedhar, S. Bhargava, Y. Iwasawa, M. Tada, and B. M. Choudary, “Aerobic Alcohol Oxidation by Ruthenium Species Stabilized on Nanocrystalline Magnesium Oxide by Basic Ionic Liquids” Adv. Synth. Catal. 350, 1225-1229 (2008).
41) M. Tada, K. Motokura, and Y. Iwasawa, “Conceptual Integration of Homogeneous and Heterogeneous Catalyses” Topic Catal. 48, 32-40 (2008).
40) K. Motokura, M. Tomita, M. Tada, and Y. Iwasawa, “Acid-Base Bifunctional Catalysis of Silica-Alumina-Supported Organic Amines for Carbon-Carbon Bond-Forming Reactions” Chem. Eur. J. 14, 4017-4027 (2008). [Synfact of the Month (Chem. Eur. J.)]
39) T. Sasaki, M. Tada, C. Zhong, T. Kume, and Y. Iwasawa, “Immobilized Metal Ion-Containing Ionic Liquids: Preparation, Structure and Catalytic Performances in Kharasch Addition Reaction and Suzuki Cross-Coupling Reactions” J. Mol. Catal. A: Chem. 279, 200-209 (2008).
38) T. E. Muller, K. Hultzsch, M. Yus, F. Foubelo, and M. Tada, “Hydroamination: Direct Addition of Amines to Alkenes and Alkynes” Chem. Rev. 108, 3795-3892 (2008).
2007
＠東京大学
37) M. Tada, and Y. Iwasawa, “Advanced Design of Catalytically Active Reaction Space at Surfaces for Selective Catalysis” Coord. Chem. Rev. 251, 2702-2716 (2007).
36) C. Zhong, T. Sasaki, A. J. Kobayashi, E. Fujiwara, A. Kobayashi, M. Tada, and Y. Iwasawa, “Syntheses, Structures, and Properties of a Series of Metal Ion-Containing Dialkylimidazolium Ionic Liquids” Bull. Chem. Soc. Jpn. 80, 2365-2374 (2007).
35) T. Yamamoto, A. Suzuki, Y. Nagai, T. Tanabe, F. Dong, Y. Inada, M. Nomura, M. Tada, and Y. Iwasawa, “Origin and Dynamics of Oxygen Storage/Release in a Pt/Ordered CeO2-ZrO2 Catalyst Studied by Time-Resolved XAFS Analysis” Angew. Chem. Int. Ed. 46, 9253-9256 (2007).
34) Y. Uemura, T. Taniike, M. Tada, Y. Morikawa, and Y. Iwasawa, “Switchover of Reaction Mechanism for the Catalytic Decomposition of HCOOH on a TiO2(110) Surface” J. Phys. Chem. C 111, 16379-16386 (2007).
33) R. Coquet, M. Tada, and Y. Iwasawa, “Energy-Gaining Formation and Catalytic Behavior of Active Structures in a SiO2-Supported Unsaturated Ru Complex Catalyst for Alkene Epoxidation by DFT Calculations” Phys. Chem. Chem. Phys. 9, 6040-6046 (2007).
32) M. Tada, R. Bal, X. Mu, R. Coquet, S. Namba, and Y. Iwasawa, “Low-Temperature PROX (Preferential Oxidation) on Novel CeO2-Supported Cu-Cluster Catalysts under Fuel-Cell Operating Conditions” Chem. Commun., 4689-4691 (2007).
31) K. Motokura, M. Tada, and Y. Iwasawa, “Heterogeneous Organic Base-Catalyzed Reactions Enhanced by Acid Supports” J. Am. Chem. Soc. 129, 9540-9541 (2007).
30) M. Tada, T. Taniike, and Y. Iwasawa, “Understanding of Novel Surface Events on a Supported Co2+-Ensemble Catalyst Promoted by Gas-Phase Molecules: Increases in the Amount and Reactivity of Adsorbed NO by CO Undetectable at the Catalyst Surface” J. Phys. Chem. C 111, 11663-11675 (2007).
29) M. Tada, R. Bal, T. Sasaki, Y. Uemura, Y. Inada, S. Tanaka, M. Nomura, and Y. Iwasawa, “Novel Re-Cluster/HZSM-5 Catalyst for Highly Selective Phenol Synthesis from Benzene and O2: Performance and Reaction Mechanism” J. Phys. Chem. C 111, 10095-10104 (2007).
28) M. Tada, R. Coquet, J. Yoshida, M. Kinoshita, and Y. Iwasawa, “Selective Formation of a Coordinatively Unsaturated Metal Complex at a Surface: A SiO2-Immobilized, Three-Coordinate Ruthenium Catalyst for Alkene Epoxidation” Angew. Chem. Int. Ed. 46, 7220-7223 (2007).
27) T. Taniike, M. Tada, R. Coquet, Y. Morikawa, T. Sasaki, and Y. Iwasawa, “A New Aspect of Heterogeneous Catalysis: Highly Reactive cis-(NO)2 Dimer and Eley-Rideal Mechanism for NO-CO Reaction on a Co-Dimer/γ-Alumina Catalyst” Chem. Phys. Lett. 443, 66-70 (2007).
26) M. Olea, M. Tada, and Y. Iwasawa, “Temporal Analysis of Products (TAP) Study on Low Temperature Carbon Monoxide Oxidation on Supported Au Catalysts” Topics Catal. 44, 137-143 (2007).
25) M. Tada, S. Murata, T. Asaoka, K. Hiroshima, K. Okumura, H. Tanida, T. Uruga, H. Nakanishi, S. Matsumoto, Y. Inada, M. Nomura, and Y. Iwasawa, “In Situ Time-Resolved Dynamic Surface Events on the Pt/C Cathode in a Fuel Cell under Operando Conditions” Angew. Chem. Int. Ed. 46, 4310-4315 (2007).
24) M. Olea, M. Tada, and Y. Iwasawa, “TAP Study on Carbon Monoxide Oxidation over Supported Gold Catalysts Au/Ti(OH)4* and Au/Fe(OH)3*: Moisture Effect” J. Catal. 248, 60-67 (2007).
23) S. Tanaka, M. Tada, and Y. Iwasawa, “Enantioselectivity Promotion by Achiral Surface Functionalization on SiO2-Supported Cu-Bis(oxazoline) Catalysts for Asymmetric Diels-Alder Reactions” J. Catal. 245, 173-183 (2007).
2006
22) C. Zhong, T. Sasaki, M. Tada, and Y. Iwasawa, “Ni Ion-Containing Ionic Liquid Salt and Ni Ion-Containing Immobilized Ionic Liquid on Silica: Application to Suzuki Cross-Coupling Reactions between Chloroarenes and Arylboronic Acids” J. Catal. 242, 357-364 (2006).
21) M. Tada, R. Bal, and Y. Iwasawa, “Catalyst Design for Selective Oxidation with Molecular Oxygen by Metal-Complex Attachment” Catal. Today 117, 141-147 (2006).
20) M. Tada, R. Bal, S. Namba, and Y. Iwasawa, “Surface-Promoted Novel Synthesis of Supported Metallic Cu Nanoparticles Active for Selective Dehydrogenation of Methanol” Appl. Catal. A: General 307, 78-84 (2006).
19) M. Tada, and Y. Iwasawa, “Advanced Chemical Design with Supported Metal Complexes for Selective Catalysis” Chem. Commun., 2833-2844 (2006). [Invited FEATURE ARTICLE] (Top Ten Access of Chem. Commun. in July 2006)
18) T. Taniike, M. Tada, Y. Morikawa, T. Sasaki, and Y. Iwasawa, “Density Functional Theoretical Calculations for a Co2/γ-Al2O3 Model Catalyst: Structures of the γ-Al2O3 Bulk and Surface and Attachment Sites for Co2+ Ions” J. Phys. Chem. B 110, 4929-4936 (2006).
17) R. Bal, M. Tada, T. Sasaki, and Y. Iwasawa, “Direct Phenol Synthesis by Selective Oxidation of Benzene with Molecular Oxygen on an Interstitial-N/Re Cluster/Zeolite Catalyst” Angew. Chem. Int. Ed. 45, 448-452 (2006). [HOT PAPER]
2005
16) M. Tada, S. Tanaka, and Y. Iwasawa, “Enantioselective Diels-Alder Reaction Promoted by Achiral Functionalization of a SiO2-Supported Cu-BOX [Bis(oxazoline)] Catalyst” Chem. Lett. 34, 1362-1363 (2005).
15) R. Bal, M. Tada, and Y. Iwasawa, “Surfactant-Promoted Novel Reductive Synthesis of Supported Metallic Cu Nanoclusters and Their Catalytic Performances for Selective Dehydrogenation of Methanol” Chem. Commun., 3433-3435 (2005).
14) M. Kotobuki, T. Shido, M. Tada, H. Uchida, H. Yamashita, Y. Iwasawa, and M. Watanabe, “XAFS Characterization of Pt-Fe/Zeolite Catalysts for Preferential Oxidation of CO in Hydrogen Fuel Gases” Catal. Lett. 103, 263-269 (2005).
13) M. Tada, N. Kojima, Y. Izumi, T. Taniike, and Y. Iwasawa, “Chiral Self-Dimerized Vanadium Complexes on a SiO2 Surface for Asymmetric Catalytic Coupling of 2-Naphthol: Structure, Performance, and Mechanism” J. Phys. Chem. B 109, 9905-9916 (2005).
12) T. Sasaki, C. Zhong, M. Tada, and Y. Iwasawa, “Immobilized Metal Ion-Containing Ionic Liquids: Preparation, Structure and Catalytic Performance in Kharasch Addition Reaction” Chem. Commun., 2506-2508 (2005).
11) S. Ichikawa, M. Tada, Y. Iwasawa, and T. Ikariya, “The Role of Carbon Dioxide in Chemoselective Hydrogenation of Halonitroaromatics over Supported Noble Metal Catalysts in Supercritical Carbon Dioxide” Chem. Commun., 924-926 (2005).
10) M. Tada, and Y. Iwasawa, “Chemical Design and In Situ Characterization of Active Surfaces for Selective Catalysis” Annu. Rev. Mater. Res. 35, 397-426 (2005).
2004
9) M. Tada, T. Taniike, L. M. Kantam, and Y. Iwasawa, “Chiral Self-Dimerization of Vanadium Complexes on a SiO2 Surface: The First Heterogeneous Catalyst for Asymmetric 2-Naphthol Coupling” Chem. Commun., 2542-2543 (2004).
8) M. Tada, M. Shimamoto, T. Sasaki, and Y. Iwasawa, “Oxide Surface-Promoted Pd-Complex Catalysis for Intramolecular O-Activated Alkene Hydroamination: Catalyst Preparation, Characterization, and Performance” Chem. Commun., 2562-2563 (2004).
7) M. Tada, T. Sasaki, and Y. Iwasawa, “Design of a Novel Molecular-Imprinted Rh-Amine Complex on SiO2 and Its Shape-Selective Catalysis for α-Methylstyrene Hydrogenation” J. Phys. Chem. B 108, 2918-2930 (2004).
2003
6) M. Tada, and Y. Iwasawa, “Approaches to Design of Active Structures by Attaching and Molecular Imprinting of Metal Complexes on Oxide Surfaces” J. Mol. Catal. A: Chem. 204-205, 27-53 (2003).
5) M. Tada, and Y. Iwasawa, “Design of Molecular-Imprinting Metal-Complex Catalysts” J. Mol. Catal. A: Chem. 199, 115-137 (2003).
2002
4) M. Tada, T. Sasaki, T. Shido, and Y. Iwasawa, “Design, Characterization and Performance of a Molecular Imprinting Rh-Dimer Hydrogenation Catalyst on a SiO2 Surface” Phys. Chem. Chem. Phys. 4, 5899-5909 (2002).
3) M. Tada, T. Sasaki, and Y. Iwasawa, “Novel SiO2-Attached Molecular-Imprinting Rh-Monomer Catalysts for Shape-Selective Hydrogenation of Alkenes; Preparation, Characterization and Performance” Phys. Chem. Chem. Phys. 4, 4561-4574 (2002).
2) M. Tada, T. Sasaki, and Y. Iwasawa, “Performance and Kinetic Behavior of a New SiO2-Attached Molecular-Imprinting Rh-Dimer Catalyst in Size- and Shape-Selective Hydrogenation of Alkenes” J. Catal. 211, 496-510 (2002).
1) A. Suzuki, M. Tada, T. Sasaki, T. Shido, and Y. Iwasawa, “Design of Catalytic Sites at Oxide Surfaces by Metal-Complex Attaching and Molecular Imprinting Techniques” J. Mol. Catal. A: Chem. 182-183, 125-136 (2002).
Books
2017
6) Y. Iwasawa, K. Asakura, M. Tada, XAFS Techniques for Catalysts, Nanomaterials, and Surfaces,Springer,(2017)
2014
6) S. Muratsugu, and M. Tada (Eds. C. Alvarez-Lorenzo), “Molecularly Imprinted Polymers as Catalysts toward Artificial Enzymes” Molecularly Imprinted Polymers: A Handbook for Academia and Industry, iSmithers, in press.
5) 唯美津木, “第11章 触媒の構造変化を捉える” 放射光が拓く化学の現在と未来, 化学同人, p.99-103 (2014).
4) 唯美津木, 笹部崇, “第2章 燃料電池 固体高分子形燃料電池MEAの新しい非破壊3次元XAFS分析法” SPring-8の高輝度放射光を利用したグリーンエネルギー分野における電池材料開発, シーエムシー出版, p.132-137 (2014).
3) M. Tada, and S. Muratsugu (Eds. K. Wilson and A. F. Lee), “Site-Isolated Heterogeneous Catalysts” Heterogeneous Catalysts for Clean Technology, Spectroscopy, Design, and Monitoring, Wiley-VCH, p.173-191 (2014).
2013
2) 唯美津木, “問題3.19 燃料電池” 問題と解説で学ぶ表面科学, 共立出版, p.122 (2013).
1) 唯美津木, 石黒志, “白金合金カソード触媒のin situリアルタイムXAFS構造解析” 次世代燃料電池開発の最前線, シーエムシー出版, p.148-154 (2013).
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